259071

Sigma-Aldrich

5,10,15,20-Tetraphenyl-21H,23H-porphine iron(III) chloride

≥94% (HPLC)

Synonym(s):
meso-Tetraphenylporphyrin iron(III) chloride
Empirical Formula (Hill Notation):
C44H28ClFeN4
CAS Number:
Molecular Weight:
704.02
MDL number:
PubChem Substance ID:
NACRES:
NA.23

Quality Level

assay

≥94% (HPLC)

λmax

418 nm

SMILES string

Cl[Fe]1n2c3ccc2c(-c4ccccc4)c5ccc(n5)c(-c6ccccc6)c7ccc(c(-c8ccccc8)c9ccc(n9)c3-c%10ccccc%10)n17

InChI

1S/C44H28N4.ClH.Fe/c1-5-13-29(14-6-1)41-33-21-23-35(45-33)42(30-15-7-2-8-16-30)37-25-27-39(47-37)44(32-19-11-4-12-20-32)40-28-26-38(48-40)43(31-17-9-3-10-18-31)36-24-22-34(41)46-36;;/h1-28H;1H;/q-2;;+3/p-1/b41-33-,41-34-,42-35-,42-37-,43-36-,43-38-,44-39-,44-40-;;

InChI key

ZDYSAMCSFRQDMN-YKKPBKTHSA-M

Packaging

500 mg in glass insert

Features and Benefits

Effective catalyst for the silylation of hydroxyl groups with hexamethyldisilazane at room temperature.

Personal Protective Equipment

dust mask type N95 (US),Eyeshields,Gloves

RIDADR

NONH for all modes of transport

WGK Germany

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

W R Scheidt et al.
Acta crystallographica. Section C, Crystal structure communications, 45 ( Pt 8), 1214-1216 (1989-08-15)
[FeCl(C44H28N4)], Mr = 704.03, monoclinic, P21/n, a = 10.254 (2), b = 15.969 (3), c = 20.810 (4) A, beta = 90.48 (2) degree, V = 3407.7 A3, Z = 4, Dx = 1.37 g cm-3, Mo K alpha, lambda...
K Tajima et al.
Biochemical and biophysical research communications, 166(2), 924-930 (1990-01-30)
Coordination reaction between linolenic-acid-hydroperoxide (LHPO) and chloro(5, 10, 15, 20-tetraphenyl)-porphyrinato iron (III), Fe(III)TPPCl, was investigated by means of ESR. ESR spectra of the ferric low-spin complex (g1 = 2.336, g2 = 2.174 and g3 = 1.929) was recorded for the...

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