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262005

Hexaammineruthenium(III) chloride

98%, powder

Synonym(s):

Hexaammineruthenium trichloride

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250 MG

$58.10

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$161.00

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$518.00

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$4,280.00

$58.10


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About This Item

Linear Formula:
[Ru(NH3)6]Cl3
CAS Number:
Molecular Weight:
309.61
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12161600
EC Number:
238-176-8
MDL number:

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Product Name

Hexaammineruthenium(III) chloride, 98%

InChI key

GBDZMMXUOBAJMN-UHFFFAOYSA-K

InChI

1S/3ClH.6H3N.Ru/h3*1H;6*1H3;/q;;;;;;;;;+3/p-3

SMILES string

N.N.N.N.N.N.[Cl-].[Cl-].[Cl-].[Ru+3]

assay

98%

form

powder

reaction suitability

core: ruthenium, reagent type: catalyst

storage temp.

2-8°C

Quality Level

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This Item
93218384050208523
reaction suitability

core: ruthenium, reagent type: catalyst

reaction suitability

-

reaction suitability

core: ruthenium, reagent type: catalyst

reaction suitability

core: ruthenium, reagent type: catalyst
reaction type: Atom Transfer Radical Polymerization (ATRP)

assay

98%

assay

-

assay

-

assay

-

form

powder

form

solid

form

powder

form

solid

Quality Level

100

Quality Level

100

Quality Level

100

Quality Level

200

storage temp.

2-8°C

storage temp.

2-8°C

storage temp.

-

storage temp.

-

General description

Hexaammineruthenium III/II (HexRu(III)|HexRu(II)) couple is a commonly used electrochemical redox couple due to its chemical and electrochemical reversibility.[1]

Application

Hexaammineruthenium(III) chloride can be used as a precursor for the preparation of:
  • Ru/Al2O3 catalyst for CO2 hydrogenation.[2]
  • Bimetallic complexes ([Ru(NH3)6][Ag(CN)2]3·2H2O).[3]
  • Chloropentaammineruthenium(III) chloride.[4]
For small scale and high throughput uses, product is also available as ChemBeads (932183)

pictograms

Exclamation mark

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

13 - Non Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves


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Juan Yao et al.
The Analyst, 142(21), 4116-4123 (2017-10-11)
An isothermal, enzyme free, ultra-specific and ultra-sensitive protocol for electrochemical detection of miRNAs is proposed based on the toehold-mediated strand displacement reaction (SDR) and non-enzymatic catalytic hairpin reaction (CHA) recycling. The SDR was first triggered only in the presence of
Measurement of the diffusion coefficients of [Ru (NH3) 6] 3+ and [Ru (NH3) 6] 2+ in aqueous solution using microelectrode double potential step chronoamperometry.
Wang Y, et al,
Journal of Electroanalytical Chemistry, 652(1-2), 13-17 (2011)
Assisted self-association of dicyanoaurate,[Au (CN) 2]-, and dicyanoargentate,[Ag (CN) 2]-, through hydrogen bonding to metal ammonia complexes
Pham D, et al.
Inorganica chimica acta, 358, 4261-4269 (2005)
Qian Yang et al.
Nanoscale, 9(46), 18523-18528 (2017-11-23)
A molecular check valve is a nanomachine that enables unidirectional molecular transport. In this work, we report a novel molecular check valve fabricated by asymmetric modification of a silica nanoporous membrane (SNM) consisting of parallel nanochannels with a diameter of
Daniel Martín-Yerga et al.
Analytica chimica acta, 981, 24-33 (2017-07-12)
In this work, we report a simple and yet efficient stencil-printed electrochemical platform that can be integrated into the caps of sample containers and thus, allows in-field quantification of Cd(II) and Pb(II) in river water samples. The device exploits the

Questions

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  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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