267406

Sigma-Aldrich

Ruthenium

sponge, −100 mesh, 99.9% trace metals basis

Synonym(s):
Ruthenium black, Ruthenium element
Empirical Formula (Hill Notation):
Ru
CAS Number:
Molecular Weight:
101.07
EC Number:
MDL number:
PubChem Substance ID:
NACRES:
NA.23

Quality Level

assay

99.9% trace metals basis

form

sponge

resistivity

7.1 μΩ-cm, 0°C

particle size

−100 mesh

bp

3900 °C (lit.)

mp

2310 °C (lit.)

density

12.45 g/cm3 (lit.)

SMILES string

[Ru]

InChI

1S/Ru

InChI key

KJTLSVCANCCWHF-UHFFFAOYSA-N

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storage_class_code

4.1B - Flammable solid hazardous materials

WGK Germany

nwg

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US),Eyeshields,Gloves

Certificate of Analysis

Certificate of Origin

Rafael E Rodríguez-Lugo et al.
Nature chemistry, 5(4), 342-347 (2013-03-21)
The development of an efficient catalytic process that mimics the enzymatic function of alcohol dehydrogenase is critical for using biomass alcohols for both the production of H2 as a chemical energy carrier and fine chemicals under waste-free conditions. Dehydrogenation of...
Lorraine Blackmore et al.
Chemical communications (Cambridge, England), 49(26), 2658-2660 (2013-02-26)
The targeted delivery of luminescent Ru(II) polypyridyl complexes to the nucleus of live mammalian cells by a Nuclear Localisation Signal (NLS) peptide; NF-κB is demonstrated.
M Beye et al.
Physical review letters, 110(18), 186101-186101 (2013-05-21)
We have studied the femtosecond dynamics following optical laser excitation of CO adsorbed on a Ru surface by monitoring changes in the occupied and unoccupied electronic structure using ultrafast soft x-ray absorption and emission. We recently reported [M. Dell'Angela et...
Lipeng Wu et al.
Journal of the American Chemical Society, 135(10), 3989-3996 (2013-02-20)
An efficient and regioselective ruthenium-catalyzed hydroaminomethlyation of olefins is reported. Key to success is the use of specific 2-phosphino-substituted imidazole ligands and triruthenium dodecacarbonyl as catalyst. Both industrially important aliphatic as well as various functionalized olefins react with primary and...
Direct synthesis of pyrroles by dehydrogenative coupling of β-aminoalcohols with secondary alcohols catalyzed by ruthenium pincer complexes.
Dipankar Srimani et al.
Angewandte Chemie (International ed. in English), 52(14), 4012-4015 (2013-03-08)
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