274623

Dess-Martin periodinane

97%

• Synonym(s): 1,1,1-Tris(acetyloxy)-1,1-dihydro-1,2-benziodoxol-3-(1H)-one
• Empirical Formula (Hill Notation): C₁₃H₁₃IO₈
• CAS Number: 87413-09-0
• Molecular Weight: 424.14
• MDL number: MFCD00130127
• PubChem Substance ID: 24856593
• NACRES: NA.22

Properties

• Quality Level: 100
• assay: 97%
• reaction suitability: reagent type: oxidant
• mp: 130-133 °C (lit.)
• storage temp.: −20°C
• SMILES string: CC(=O)OI1(OC(C)=O)(OC(C)=O)OC(=O)c2ccccc12
• InChI: 1S/C13H13IO8/c1-8(15)19-14(20-9(2)16,21-10(3)17)12-7-5-4-6-11(12)13(18)22-14/h4-7H,1-3H3
• InChI key: NKLCNNUWBJBICK-UHFFFAOYSA-N

Description

Packaging

5, 25, 50, 250 g in glass bottle

Application

Oxidizing agent for 1° and 2° alcohols to aldehydes and ketones.

Used for the oxidation of hydroxychlorins to chlorin-α-diones and tetraones.

Safety Information

• Pictograms: GHS03,GHS07
• Signal Word: Danger
• Hazard Statements: H272 - H315 - H319 - H335
• Precautionary Statements: P210 - P220 - P261 - P264 - P302 + P352 - P305 + P351 + P338
• Hazard Classifications: Eye Irrit. 2 - Ox. Sol. 2 - Skin Irrit. 2 - STOT SE 3
• Target Organs: Respiratory system
• Storage Class Code: 5.1B - Oxidizing hazardous materials
• WGK: WGK 3
• Flash Point(F): Not applicable
• Flash Point(C): Not applicable
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves