275867

5,10,15,20-Tetrakis(4-methoxyphenyl)-21H,23H-porphine cobalt(II)

• Empirical Formula (Hill Notation): C₄₈H₃₆CoN₄O₄
• CAS Number: 28903-71-1
• Molecular Weight: 791.76
• NACRES: NA.23
• PubChem Substance ID: 24856676
• UNSPSC Code: 12352103
• MDL number: MFCD00010724

Properties

• form: solid
• reaction suitability: reagent type: catalyst; core: cobalt
• λmax: 417 nm, 530 nm (2nd)
• SMILES string: COc1ccc(cc1)-c2c3ccc(n3)c(-c4ccc(OC)cc4)c5ccc6c(-c7ccc(OC)cc7)c8ccc(n8)c(-c9ccc(OC)cc9)c%10ccc2n%10[Co]n56
• InChI: 1S/C48H36N4O4.Co/c1-53-33-13-5-29(6-14-33)45-37-21-23-39(49-37)46(30-7-15-34(54-2)16-8-30)41-25-27-43(51-41)48(32-11-19-36(56-4)20-12-32)44-28-26-42(52-44)47(40-24-22-38(45)50-40)31-9-17-35(55-3)18-10-31;/h5-28H,1-4H3;/q-2;+2/b45-37-,45-38-,46-39-,46-41-,47-40-,47-42-,48-43-,48-44-;
• InChI key: QBCIMRXPMLWVML-NHZJRHMYSA-N

Description

Application

Starting material in the synthesis of cobalt nitrosyl porphyrins for use in the study of the binding and activation of nitric oxide.

Features and Benefits

Acts as a versatile catalyst during the oxidation of a wide range of organic substrates with dioxygen in the presence of 2-methylpropanal under ambient conditions.

Safety Information

• Storage Class: 11 - Combustible Solids
• wgk: WGK 3
• flash_point_f: Not applicable
• flash_point_c: Not applicable
• ppe: Eyeshields, Gloves, type N95 (US)