281042

Sigma-Aldrich

Tetradecafluorohexane

99%

Synonym(s):
Perfluorohexane
Linear Formula:
CF3(CF2)4CF3
CAS Number:
Molecular Weight:
338.04
Beilstein/REAXYS Number:
1802113
EC Number:
MDL number:
PubChem Substance ID:
NACRES:
NA.22
Pricing and availability is not currently available.

Quality Level

assay

99%

refractive index

n20/D 1.252 (lit.)

bp

58-60 °C (lit.)

mp

-74 °C (lit.)

density

1.669 g/mL at 25 °C (lit.)

SMILES string

FC(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F

InChI

1S/C6F14/c7-1(8,3(11,12)5(15,16)17)2(9,10)4(13,14)6(18,19)20

InChI key

ZJIJAJXFLBMLCK-UHFFFAOYSA-N

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General description

Tetradecafluorohexane in the gas phase reacts spontaneously with lithium amalgam, to give a solid and intimate mixture of lithium fluoride and elemental polymeric carbon with a small amount of superstoichiometric lithium.

Application

Tetradecafluorohexane has been used:
  • as a fluorocarbon organic solvent in the preparation of temperature-induced phase-separation solution
  • to investigate boiling heat transfer mechanisms
  • as a photosensitizer in fluorous biphasic singlet oxygenation
  • as a novel reaction medium for photooxidation reactions

Packaging

25 mL in ampule

Hazard Statements

Precautionary Statements

Personal Protective Equipment

dust mask type N95 (US),Eyeshields,Gloves

Hazard Codes

Xi

Risk Statement

36/37/38

Safety Statement

26-36

RIDADR

NONH for all modes of transport

WGK Germany

WGK 2

Michael P Grubb et al.
Nature chemistry, 8(11), 1042-1046 (2016-10-22)
Spectroscopically observing the translational and rotational motion of solute molecules in liquid solutions is typically impeded by their interactions with the solvent, which conceal spectral detail through linewidth broadening. Here we show that unique insights into solute dynamics can be...
Journal of the American Chemical Society, 118, 5312-5312 (1996)
Journal of Heat Transfer, 118, 429-429 (1996)
Synthetic Communications, 26, 1861-1861 (1996)
Xia Wang et al.
Biomaterials, 34(8), 2057-2068 (2012-12-19)
Au nanoparticles-coated, perfluorohexane-encapsulated and PEGylated mesoporous silica nanocapsule-based enhancement agents (MSNC@Au-PFH-PEG, abb. as MAPP) have been synthesized, for the ultrasound-induced cytoclasis, contrast-intensified ultrasound (US) imaging and US-guided high intensity focused ultrasound (HIFU) surgical therapy. Both the US-induced thermal effect and...

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