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281697

(R)-(−)-2-Pyrrolidinemethanol

99%

Synonym(s):

(R)-(−)-2-(Hydroxymethyl)pyrrolidine, D-Prolinol

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$72.52

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About This Item

Empirical Formula (Hill Notation):
C5H11NO
CAS Number:
68832-13-3
Molecular Weight:
101.15
Beilstein/REAXYS Number:
1523669
MDL number:
MFCD00064321
UNSPSC Code:
12352005
PubChem Substance ID:
24856990
NACRES:
NA.22

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Quality Level

100

assay

99%

optical activity

[α]20/D −31°, c = 1 in toluene

refractive index

n20/D 1.4849 (lit.)

bp

74-76 °C/2 mmHg (lit.)

density

1.025 g/mL at 25 °C (lit.)

functional group

hydroxyl

SMILES string

OC[C@H]1CCCN1

InChI

1S/C5H11NO/c7-4-5-2-1-3-6-5/h5-7H,1-4H2/t5-/m1/s1

InChI key

HVVNJUAVDAZWCB-RXMQYKEDSA-N

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1 of 4

This Item
186511761990532169
(R)-(−)-2-Pyrrolidinemethanol 99%

Sigma-Aldrich

281697

(R)-(−)-2-Pyrrolidinemethanol

(S)-(+)-2-Pyrrolidinemethanol 97%

Sigma-Aldrich

186511

(S)-(+)-2-Pyrrolidinemethanol

(R)-1-Methyl-2-pyrrolidinemethanol 97%

Sigma-Aldrich

761990

(R)-1-Methyl-2-pyrrolidinemethanol

(R)-(−)-N-Boc-3-pyrrolidinol 98%

Sigma-Aldrich

532169

(R)-(−)-N-Boc-3-pyrrolidinol

assay

99%

assay

97%

assay

97%

assay

98%

Quality Level

100

Quality Level

100

Quality Level

100

Quality Level

100

refractive index

n20/D 1.4849 (lit.)

refractive index

n20/D 1.4853 (lit.)

refractive index

n20/D 4.469

refractive index

-

bp

74-76 °C/2 mmHg (lit.)

bp

74-76 °C/2 mmHg (lit.)

bp

68-71 °C (lit.)

bp

-

density

1.025 g/mL at 25 °C (lit.)

density

1.025 g/mL at 25 °C (lit.)

density

0.971 g/mL at 25 °C

density

-

optical activity

[α]20/D −31°, c = 1 in toluene

optical activity

[α]20/D +31°, c = 1 in toluene

optical activity

-

optical activity

[α]20/D −26±1, c = 1 in methanol

Application

Versatile reagent for asymmetric synthesis.[1][2]

pictograms

Exclamation mark
GHS07

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

10 - Combustible liquids

wgk_germany

WGK 3

flash_point_f

186.8 °F - closed cup

flash_point_c

86 °C - closed cup

ppe

Eyeshields, Gloves, type ABEK (EN14387) respirator filter

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Certificates of Analysis (COA)

Lot/Batch Number
STBB4216V
MKBB4574V
STBB4216
MKBB4574
13821LH

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Tetrahedron Asymmetry, 15, 519-523 (2004)
Silvia Dei et al.
Bioorganic & medicinal chemistry, 11(14), 3153-3164 (2003-06-24)
Four out of the eight possible stereoisomers of 1-methyl-2-(2-methyl-1,3-dioxolan-4-yl)pyrrolidine, 1-methyl-2-(2-methyl-1,3-oxathiolan-5-yl)pyrrolidine and the corresponding iodomethylates have been synthesised. They were formally derived from hybridisation of potent though unselective agonists studied before, such as 1,3-dioxolane 1 and 1,3-oxathiolane 2, with the structure
Emily M Christensen et al.
The Journal of biological chemistry, 295(52), 18316-18327 (2020-10-29)
Pyrroline-5-carboxylate reductase 1 (PYCR1) catalyzes the biosynthetic half-reaction of the proline cycle by reducing Δ1-pyrroline-5-carboxylate (P5C) to proline through the oxidation of NAD(P)H. Many cancers alter their proline metabolism by up-regulating the proline cycle and proline biosynthesis, and knockdowns of

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