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281999

4-Bromobiphenyl

98%

Synonym(s):

(4-Bromophenyl)benzene, 1-Bromo-4-phenylbenzene, 4-Biphenyl bromide, 4′-Bromobiphenyl, p-Phenylphenyl bromide

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About This Item

Linear Formula:
C6H5C6H4Br
CAS Number:
Molecular Weight:
233.10
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
202-176-6
Beilstein/REAXYS Number:
1907453
MDL number:
Assay:
98%
Form:
solid
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Quality Segment

assay

98%

form

solid

bp

310 °C (lit.)

mp

82-86 °C (lit.)

functional group

bromo, phenyl

SMILES string

Brc1ccc(cc1)-c2ccccc2

InChI

1S/C12H9Br/c13-12-8-6-11(7-9-12)10-4-2-1-3-5-10/h1-9H

InChI key

PKJBWOWQJHHAHG-UHFFFAOYSA-N

General description

In vitro metabolism of 4-bromobiphenyl by cytochrome P-450-dependent monooxygenases in rat hepatic microsomes has been investigated[1]. 4-Bromobiphenyl undergoes reduction to biphenyl in cationic micelles (cetyltrimethyl-ammonium bromide) by electrochemically generated anion radicals of 9-phenylanthracene.

Application

4-Bromobiphenyl was used in the synthesis of 4-biphenylthiolate[1].

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This Item
255386252247102741
assay

98%

assay

97%

assay

96%

assay

96%

Quality Level

100

Quality Level

100

Quality Level

100

Quality Level

100

mp

82-86 °C (lit.)

mp

-

mp

1.5-2 °C (lit.)

mp

71-74 °C (lit.)

bp

310 °C (lit.)

bp

103-104 °C/0.2 mmHg (lit.)

bp

297-298 °C (lit.)

bp

248 °C (lit.)

form

solid

form

liquid

form

liquid

form

solid

functional group

bromo

functional group

bromo, phenyl

functional group

bromo, phenyl

functional group

fluoro, phenyl


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Danger

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Acute 1 - Eye Dam. 1 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

11 - Combustible Solids

wgk

WGK 3

ppe

dust mask type N95 (US), Eyeshields, Gloves



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Questions

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  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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