282146

(1R)-(−)-10-Camphorsulfonic acid

98%

• Synonym(s): (−)-Camphor-10-sulfonic acid, (1R)-(−)-Camphor-10-sulfonic acid, (1R)-Camphor-10-sulfonic acid
• Empirical Formula (Hill Notation): C₁₀H₁₆O₄S
• CAS Number: 35963-20-3
• Molecular Weight: 232.30
• Beilstein: 2809676
• EC Number: 252-817-9
• MDL number: MFCD00064158
• PubChem Substance ID: 24857020
• NACRES: NA.22

Properties

• Quality Level: 100
• Assay: 98%
• optical activity: [α]20/D −21°, c = 2 in H₂O
• mp: 198 °C (dec.) (lit.)
• SMILES string: [H][C@]12CC[C@](CS(O)(=O)=O)(C(=O)C1)C2(C)C
• InChI: 1S/C10H16O4S/c1-9(2)7-3-4-10(9,8(11)5-7)6-15(12,13)14/h7H,3-6H2,1-2H3,(H,12,13,14)/t7-,10-/m0/s1
• InChI key: MIOPJNTWMNEORI-XVKPBYJWSA-N

Description

General description

(1R)-(−)-10-Camphorsulfonic acid is an HPLC derivatization reagent for UV/Vis detection. It is mainly employed for the resolution of bases.

Application

(1R)-(−)-10-Camphorsulfonic acid may be used as a chiral building block for the synthesis of pentavalent organo-bismuth derivatives by enantioselective C-arylation. It may be used as a chiral monomer in the enantioselective sensing of chiral amino acids by potentiometric sensors based on optical active polyaniline films.

Safety Information

• Pictograms: GHS05
• Signal Word: Danger
• Hazard Statements: H314
• Precautionary Statements: P260 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338 - P363
• Hazard Classifications: Eye Dam. 1 - Skin Corr. 1B
• Storage Class Code: 8A - Combustible, corrosive hazardous materials
• WGK: WGK 3
• Flash Point(F): Not applicable
• Flash Point(C): Not applicable
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves