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282235

Sigma-Aldrich

Methylmagnesium bromide solution

1.4 M in THF: toluene (1:3)

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Synonym(s):
Bromomethylmagnesium
Linear Formula:
CH3MgBr
CAS Number:
Molecular Weight:
119.24
Beilstein/REAXYS Number:
3535220
MDL number:
PubChem Substance ID:

Quality Level

reaction suitability

reaction type: Grignard Reaction

concentration

1.4 M in THF: toluene (1:3)

density

1.018 g/mL at 25 °C

SMILES string

C[Mg]Br

InChI

1S/CH3.BrH.Mg/h1H3;1H;/q;;+1/p-1

InChI key

AVFUHBJCUUTGCD-UHFFFAOYSA-M

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1 of 4

This Item
189898302430703583
vibrant-m

282235

Methylmagnesium bromide solution

vibrant-m

189898

Methylmagnesium bromide solution

vibrant-m

302430

Methylmagnesium bromide solution

vibrant-m

703583

Methylmagnesium bromide solution

Quality Level

200

Quality Level

200

Quality Level

100

Quality Level

100

density

1.018 g/mL at 25 °C

density

1.035 g/mL at 25 °C

density

0.856 g/mL at 25 °C

density

1.117 g/mL at 25 °C

reaction suitability

reaction type: Grignard Reaction

reaction suitability

reaction type: Grignard Reaction

reaction suitability

reaction type: Grignard Reaction

reaction suitability

reaction type: Grignard Reaction

Application

Methylmagnesium bromide is generally used as a Grignard reagent for C-C bond formation by reacting with the carbonyl groups of aldehydes and ketones.

signalword

Danger

Hazard Classifications

Aquatic Chronic 3 - Asp. Tox. 1 - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Repr. 2 - Skin Corr. 1B - STOT RE 2 - STOT SE 3 - Water-react 1

target_organs

Central nervous system, Respiratory system

supp_hazards

Storage Class

4.3 - Hazardous materials, which set free flammable gases upon contact with water

wgk_germany

WGK 3

flash_point_f

1.4 °F - closed cup

flash_point_c

-17 °C - closed cup

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter


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