282235

Sigma-Aldrich

Methylmagnesium bromide solution

1.4 M in THF: toluene (1:3)

Linear Formula:
CH3MgBr
CAS Number:
Molecular Weight:
119.24
Beilstein/REAXYS Number:
3535220
MDL number:
PubChem Substance ID:
Pricing and availability is not currently available.

Quality Level

reaction suitability

reaction type: Grignard Reaction

concentration

1.4 M in THF: toluene (1:3)

density

1.018 g/mL at 25 °C

SMILES string

C[Mg]Br

InChI

1S/CH3.BrH.Mg/h1H3;1H;/q;;+1/p-1

InChI key

AVFUHBJCUUTGCD-UHFFFAOYSA-M

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Application

Methylmagnesium bromide is generally used as a Grignard reagent for C-C bond formation by reacting with the carbonyl groups of aldehydes and ketones.

Packaging

100, 800 mL in Sure/Seal™

Signal Word

Danger

Target Organs

Central nervous system

Supp Hazards

EUH014 - EUH018 - EUH019

Personal Protective Equipment

dust mask type N95 (US),Eyeshields,Gloves

RIDADR

UN 3399A 4.3(3) / PGI

WGK Germany

WGK 2

Flash Point(F)

1.4 °F - closed cup

Flash Point(C)

-17 °C - closed cup

Certificate of Analysis
Certificate of Origin
Alcohols: Reactions and Synthesis
Organic Chemistry Study Guide: Key Concepts, Problems, and Solutions (2015)
Snahel Patel et al.
Journal of medicinal chemistry, 58(1), 401-418 (2014-10-24)
Dual leucine zipper kinase (DLK, MAP3K12) was recently identified as an essential regulator of neuronal degeneration in multiple contexts. Here we describe the generation of potent and selective DLK inhibitors starting from a high-throughput screening hit. Using proposed hinge-binding interactions...

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