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282782

Platinum(II) acetylacetonate

97%

Synonym(s):

2,4-Pentanedione platinum(II) derivative, Pt(acac)2

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Size/SKUAvailabilityPrice
500 mg
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$131.00
5 g
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$637.00

About This Item

Linear Formula:
Pt(C5H7O2)2
CAS Number:
Molecular Weight:
393.29
UNSPSC Code:
12352103
NACRES:
NA.23
PubChem Substance ID:
EC Number:
239-223-5
Beilstein/REAXYS Number:
4136189
MDL number:

$131.00


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Quality Segment

assay

97%

form

solid

reaction suitability

core: platinum, reagent type: catalyst

mp

249-252 °C (lit.)

SMILES string

CC(=O)\C=C(\C)O[Pt]O\C(C)=C/C(C)=O

InChI

1S/2C5H8O2.Pt/c2*1-4(6)3-5(2)7;/h2*3,6H,1-2H3;/q;;+2/p-2/b2*4-3-;

InChI key

KLFRPGNCEJNEKU-FDGPNNRMSA-L

General description

Platinum(II)acetylacetonate is widely used as a Ptsource and precursor in the preparation of nanocatalysts and films. It is alsoused as a catalyst in N-allylation reactions.

Application

Platinum(II)acetylacetonate can be used as an efficient catalyst:
  • In the preparation of N-allylanilines by the direct use of allylic alcohols. Anilines with electron-donating groups give good yields.
  • For selective N-allylation of 2,3-disubstituted indoles in water.
Pt-loaded ZnO thick films can be prepared by flame spray pyrolysis method using zinc naphthenate and platinum(II) acetylacetonate as precursors. These sensing films can be used for acetylene detection and show good selectivity towards carbon monoxide, hydrogen, and methane.

It can be used as a starting material in the preparation of platinum-lead nanoparticles supported on carbon. The PtPb/C catalyst exhibits enhanced electrochemical activity towards methanol and formic acid oxidation.

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This Item
523038401684921025
form

solid

form

-

form

powder

form

-

assay

97%

assay

≥99.98% trace metals basis

assay

-

assay

≥99.9% trace metals basis

mp

249-252 °C (lit.)

mp

249-252 °C (lit.)

mp

141-144 °C (lit.)

mp

200-251 °C (dec.)

Quality Level

100

Quality Level

100

Quality Level

100

Quality Level

200

reaction suitability

core: platinum

reaction suitability

core: platinum

reaction suitability

core: lead, reagent type: catalyst

reaction suitability

core: palladium


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Health hazardExclamation mark

signalword

Warning

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Irrit. 2 - Repr. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

11 - Combustible Solids

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type P3 (EN 143) respirator cartridges



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Questions

1–3 of 3 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

      Helpful?

  3. What is the shelf life for Platinum acetylacetonate? In how much time it normally expires? How it should be stored?

    1 answer
    1. The composition information for this product is considered proprietary. However, upon review of the literature is does appear unlikely.

      Helpful?

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