283630

Sigma-Aldrich

Vinylferrocene

97%

Empirical Formula (Hill Notation):
C12H12Fe
CAS Number:
Molecular Weight:
212.07
EC Number:
MDL number:
PubChem Substance ID:
NACRES:
NA.22
Pricing and availability is not currently available.

Quality Level

assay

97%

reaction suitability

core: iron
reagent type: catalyst

bp

80-85 °C/0.2 mmHg (lit.)

mp

51-53 °C (lit.)

SMILES string

[Fe].[CH]1[CH][CH][CH][CH]1.C=C[C]2[CH][CH][CH][CH]2

InChI

1S/C7H7.C5H5.Fe/c1-2-7-5-3-4-6-7;1-2-4-5-3-1;/h2-6H,1H2;1-5H;

InChI key

LCPVTGDQYVLJHU-UHFFFAOYSA-N

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Packaging

1, 5 g in glass bottle

Application

Synthesis of 2-aminomethylferrocenes from vinyl ferrocene and lithium amides.

Pictograms

Flame

Signal Word

Danger

Hazard Statements

Precautionary Statements

Personal Protective Equipment

dust mask type N95 (US),Eyeshields,Gloves

RIDADR

UN1325 - class 4.1 - PG 2 - Flammable solids, organic, n.o.s., HI: all

WGK Germany

WGK 3

Flash Point(F)

143.6 °F - closed cup

Flash Point(C)

62 °C - closed cup

Ceren Kaçar et al.
Analytical and bioanalytical chemistry, 409(11), 2873-2883 (2017-02-12)
Highly sensitive L-lysine enzyme electrodes were constructed by using poly(vinylferrocene)-multiwalled carbon nanotubes-gelatine (PVF/MWCNTs-GEL) and poly(vinylferrocene)-multiwalled carbon nanotubes-gelatine-graphene (PVF/MWCNTs-GEL/GR) composites as sensing interfaces and their performances were evaluated. Lysine oxidase (LO) was immobilized onto the composite modified glassy carbon electrodes (GCE)...
Joachim Loup et al.
Angewandte Chemie (International ed. in English), 56(45), 14197-14201 (2017-09-19)
Highly enantioselective iron-catalyzed C-H alkylations by inner-sphere C-H activation were accomplished with ample scope. High levels of enantiocontrol proved viable through a novel ligand design that exploits a remote meta-substitution on N-heterocyclic carbenes within a facile ligand-to-ligand H-transfer C-H cleavage.
Ryoji Kurita et al.
Biosensors & bioelectronics, 20(3), 518-523 (2004-10-21)
This paper proposes a very simple procedure for preparing a biocompatible sensor based on a protein (bovine serum albumin, BSA), enzyme and vinylferrocene (VF) composite membrane modified electrode. The membrane was prepared simply by first casting vinylferrocene and then coating...
Takanori Tamaki et al.
The journal of physical chemistry. B, 111(34), 10312-10319 (2007-08-10)
We immobilized hydroquinone through a spacer to polymer grafted on carbon black and achieved a high-surface-area biofuel cell electrode. Quinone compounds are well-known to transfer electrons in the respiratory chain and have been considered prospective mediators in biofuel cells because...
Kay L Robinson et al.
Analytical sciences : the international journal of the Japan Society for Analytical Chemistry, 24(3), 339-343 (2008-03-12)
Poly(vinylferrocene) (pVFc) homopolymer was synthesized by free radical polymerization, along with a series of pVFc-based copolymers containing either styrene, vinylanthracene or methylmethacrylate. This report details the electrochemical experiments conducted to examine the stability of the various pVFc based polymers, which...

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