288403

Sigma-Aldrich

trans-Dichlorobis(triphenylphosphine)platinum(II)

Synonym(s):
trans-Bis(triphenylphosphine)platinum dichloride
Linear Formula:
[(C6H5)3P]2PtCl2
CAS Number:
Molecular Weight:
790.56
MDL number:
PubChem Substance ID:
NACRES:
NA.22
Pricing and availability is not currently available.

reaction suitability

core: platinum
reagent type: catalyst

SMILES string

Cl[Pt]Cl.c1ccc(cc1)P(c2ccccc2)c3ccccc3.c4ccc(cc4)P(c5ccccc5)c6ccccc6

InChI

1S/2C18H15P.2ClH.Pt/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;;/h2*1-15H;2*1H;/q;;;;+2/p-2

InChI key

XAFJSPPHVXDRIE-UHFFFAOYSA-L

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Application

Catalyst for:
  • Preparation of soluble polymers of monosubstituted acetylenes with quaternary ammonium pendant groups
  • Alkynylation and hydrogenation reactions
  • Hetero-Diels-Alder/ring-opening reactions
  • Insertion of carbenes into O-H bonds of alcohols
  • Cyclopropanation of olefins
  • Hydroformylation reactions

Packaging

1 g in glass bottle

Pictograms

Exclamation markHealth hazard

Signal Word

Danger

Target Organs

Respiratory system

Personal Protective Equipment

dust mask type N95 (US),Eyeshields,Gloves

RIDADR

NONH for all modes of transport

WGK Germany

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Certificate of Analysis
Certificate of Origin

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