294012
tert-Butyl methyl sulfide
97%
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About This Item
Linear Formula:
(CH3)3CSCH3
CAS Number:
Molecular Weight:
104.21
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
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assay
97%
refractive index
n20/D 1.44 (lit.)
bp
101-102 °C (lit.)
density
0.826 g/mL at 25 °C (lit.)
SMILES string
CSC(C)(C)C
InChI
1S/C5H12S/c1-5(2,3)6-4/h1-4H3
InChI key
CJFVCTVYZFTORU-UHFFFAOYSA-N
General description
Alloxazine-cyclodextrin conjugate catalyzed enantioselective oxidation of tert-butyl methyl sulfide has been reported[1].
signalword
Danger
hcodes
Hazard Classifications
Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
Storage Class
3 - Flammable liquids
wgk_germany
WGK 3
flash_point_f
24.8 °F - closed cup
flash_point_c
-4 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
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Viktor Mojr et al.
Organic & biomolecular chemistry, 9(21), 7318-7326 (2011-09-01)
Four structurally different alloxazine-cyclodextrin conjugates were prepared and tested as catalysts for the enantioselective oxidation of prochiral sulfides to sulfoxides by hydrogen peroxide in aqueous solutions. The alloxazinium unit was appended to the primary face of α- and β-cyclodextrins via
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