294934

Sigma-Aldrich

Dipropyl carbonate

99%

Linear Formula:
(CH3CH2CH2O)2CO
CAS Number:
Molecular Weight:
146.18
EC Number:
MDL number:
PubChem Substance ID:
NACRES:
NA.22
Pricing and availability is not currently available.

Quality Level

assay

99%

refractive index

n20/D 1.401 (lit.)

bp

167-168 °C (lit.)

density

0.944 g/mL at 25 °C (lit.)

SMILES string

CCCOC(=O)OCCC

InChI

1S/C7H14O3/c1-3-5-9-7(8)10-6-4-2/h3-6H2,1-2H3

InChI key

VUPKGFBOKBGHFZ-UHFFFAOYSA-N

General description

Thermal decomposition of dipropyl carbonate at 300-400°C yields carbon dioxide, alkene and alcohol. Dipropyl carbonate reacts with hydrous titanium dioxide (TiO2 ·nH2O, n=0.15-1.23) at 453-573K to yield titanium tetraalkoxides [Ti(OPrn)4]. N435-catalyzed transesterification of diethyl carbonate with dipropyl carbonate to form ethyl propyl carbonate has been reported.

Packaging

5 g in glass bottle

Pictograms

FlameExclamation mark

Signal Word

Warning

Target Organs

Respiratory system

Personal Protective Equipment

dust mask type N95 (US),Eyeshields,Gloves

RIDADR

UN 3272 3 / PGIII

WGK Germany

WGK 3

Flash Point(F)

131.0 °F - closed cup

Flash Point(C)

55 °C - closed cup

The thermal decomposition of simple carbonate esters.
Cross JTD, et al.
Australian Journal of Chemistry, 29(7), 1477-1481 (1976)
Controlled lipase-catalyzed synthesis of poly (hexamethylene carbonate).
Jiang Z, et al.
Macromolecules, 40(22), 7934-7943 (2007)
Synthesis of titanium tetraalkoxides from hydrous titanium dioxideand dialkyl carbonates.
Suzuki E, et al.
Journal of Materials Chemistry, 7(10), 2049-2051 (1997)

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