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298212

Sigma-Aldrich

Copper(I) thiocyanate

Copper(I) thiocyanate

99%

Synonym(s):

Cuprous thiocyanate

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50 G
$103.00
250 G
$411.35

About This Item

Linear Formula:
CuSCN
CAS Number:
Molecular Weight:
121.63
EC Number:
MDL number:
UNSPSC Code:
12352302
PubChem Substance ID:
NACRES:
NA.23
assay:
99%
form:
powder

$103.00


In StockDetails


Request a Bulk Order

Quality Level

assay

99%

form

powder

application(s)

battery manufacturing

SMILES string

[Cu]SC#N

InChI

1S/CHNS.Cu/c2-1-3;/h3H;/q;+1/p-1

InChI key

PDZKZMQQDCHTNF-UHFFFAOYSA-M

General description

The crystal belongs to the orthorhombic system, space group: Pbca,a=10.994(9)Å, b=7.224(3)Å,c=6.662(2)Å. [1]

Application

The product can be prepared from Cu(CH3COO)2·H2O, AgNO3, NH4NCS and im(im = imidazole). The structure and optical properties were reported. [2] It is an air- and light-stable source of Cu(I).

pictograms

Environment

signalword

Warning

hcodes

Hazard Classifications

Aquatic Acute 1 - Aquatic Chronic 1

supp_hazards

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves


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Synthesis, structure and non-linear optical property of a copper(II) thiocyanate three-dimensional supramolecular compound
Bie HY, et al.
Journal of Molecular Structure, 660, 107-112 (2003)
Graham A Bowmaker et al.
Dalton transactions (Cambridge, England : 2003), (39)(39), 5290-5292 (2008-10-02)
The role of short-range diffusion in solvent-assisted mechanochemical synthesis is demonstrated in studies of a polymorphic transition and a ligand dissociation reaction involving copper(I) thiocyanate complexes.
S Bacon
Journal of human nutrition, 34(6), 445-449 (1980-12-01)
The advantages and disadvantages of faecal markers that are available in the UK are discussed. Opinions and comments from units using them are included.
The crystal structure of copper(I) thiocyanate and its relation to the crystal structure of copper(II) diammine dithiocyanate complex
Kabesova M, et al.
Inorgorganica Chimica Acta, 17, 161-165 (1976)
Graham A Bowmaker et al.
Dalton transactions (Cambridge, England : 2003), 41(25), 7513-7525 (2012-05-24)
A number of adducts of copper(I) thiocyanate with bulky tertiary phosphine ligands, and some nitrogen-base solvates, were synthesized and structurally and spectroscopically characterised. CuSCN:PCy3 (1:2), as crystallized from pyridine, is shown by a single crystal X-ray study to be a

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