If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf
302120
n-Butyllithium solution
2.0 M in cyclohexane
Synonym(s):
n-BuLi, Butyl lithium, Butyllithium solution, Lithium-1-butanide
Select a Size
| Pack Size | SKU | Availability | Price |
|---|---|---|---|
| 4 x 25 mL | Check Cart for Availability | $76.90 | |
| 100 mL | Check Cart for Availability | $82.10 | |
| 800 mL | Check Cart for Availability | $237.00 |
About This Item
form
liquid
Quality Level
concentration
2.0 M in cyclohexane
bp
80 °C
density
0.775 g/mL at 25 °C
storage temp.
2-8°C
SMILES string
[Li]CCCC
InChI
1S/C4H9.Li/c1-3-4-2;/h1,3-4H2,2H3;
InChI key
MZRVEZGGRBJDDB-UHFFFAOYSA-N
General description
Application
- A polymerization initiator to synthesize polystyrenes by anionic polymerization of styrene.
- A strong base in the diastereoselective alkylation reactions.
- A reagent to synthesize 2-benzoylpyrroles by reacting benzaldehydes with di(1H-pyrrol-1-yl)zirconium(IV) chloride complex.
Packaging
Legal Information
1 of 1
This Item | |||
|---|---|---|---|
| concentration 2.0 M in cyclohexane | concentration 2.5 M in hexanes | concentration 10.7 M in hexanes | concentration 1.6 M in hexanes |
| Quality Level 200 | Quality Level 200 | Quality Level 100 | Quality Level 200 |
| form liquid | form liquid | form liquid | form liquid |
| storage temp. 2-8°C | storage temp. 2-8°C | storage temp. 2-8°C | storage temp. 2-8°C |
| bp 80 °C | bp - | bp - | bp - |
| density 0.775 g/mL at 25 °C | density 0.693 g/mL at 25 °C | density 0.761 g/mL at 25 °C | density 0.68 g/mL at 25 °C |
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signalword
Danger
target_organs
Central nervous system
supp_hazards
Storage Class
4.3 - Hazardous materials which set free flammable gases upon contact with water
flash_point_f
-0.4 °F - closed cup
flash_point_c
-18 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
Hazard Classifications
Aquatic Acute 1 - Aquatic Chronic 1 - Asp. Tox. 1 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3 - Water-react. 1
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Articles
Transformative reagents enable selective conversions within molecules containing sensitive functionalities under mild reactions.
Global Trade Item Number
| SKU | GTIN |
|---|---|
| 302120-100ML | 04061837881015 |
| 302120-4X25ML | 04061826665725 |
| 302120-800ML | 04061837881022 |
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How can I determine the shelf life / expiration / retest date of this product?
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How is shipping temperature determined? And how is it related to the product storage temperature?
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Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf
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