Yes, it is water soluble. While we have not tested the upper limits of the solubility, we use water as the solvent for the spectrophotometric assay performed on each lot of this product. For a recent lot, approximately 6 milligrams of the powder was accurately measured and dissolved in exactly 100 mL of water, to give a solution that was 0.06 mg/mL. Then, a portion of that was diluted 10-fold, and the absorbance of the resulting 0.006 mg/mL solution was read. The lambda max for each lot is measured, and it is consistently in the range of 410 - 414 nm. (Concentrations as low as 0.002 mg/mL could be used.) Please see the certificate of analysis (CofA) for the lambda max as well as the measured extinction coefficient for each lot.
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5,10,15,20-Tetrakis(4-trimethylammoniophenyl)porphyrin tetra(p-toluenesulfonate)
Dye content 90 %, powder
Synonym(s):
TTMAPP
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100 MG
$342.00
About This Item
Empirical Formula (Hill Notation):
C84H90N8O12S4
CAS Number:
Molecular Weight:
1531.92
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12161600
MDL number:
Beilstein/REAXYS Number:
6378804
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Product Name
5,10,15,20-Tetrakis(4-trimethylammoniophenyl)porphyrin tetra(p-toluenesulfonate), Dye content 90 %
InChI
1S/C56H62N8.4C7H8O3S/c1-61(2,3)41-21-13-37(14-22-41)53-45-29-31-47(57-45)54(38-15-23-42(24-16-38)62(4,5)6)49-33-35-51(59-49)56(40-19-27-44(28-20-40)64(10,11)12)52-36-34-50(60-52)55(48-32-30-46(53)58-48)39-17-25-43(26-18-39)63(7,8)9;4*1-6-2-4-7(5-3-6)11(8,9)10/h13-36,57,60H,1-12H3;4*2-5H,1H3,(H,8,9,10)/q+4;;;;/p-4/b53-45-,53-46-,54-47-,54-49-,55-48-,55-50-,56-51-,56-52-;;;;
SMILES string
Cc1ccc(cc1)S([O-])(=O)=O.Cc2ccc(cc2)S([O-])(=O)=O.Cc3ccc(cc3)S([O-])(=O)=O.Cc4ccc(cc4)S([O-])(=O)=O.C[N+](C)(C)c5ccc(cc5)-c6c7ccc(n7)c(-c8ccc(cc8)[N+](C)(C)C)c9ccc([nH]9)c(-c%10ccc(cc%10)[N+](C)(C)C)c%11ccc(n%11)c(-c%12ccc(cc%12)[N+](C)(C)C)c%13ccc6[nH]%13
InChI key
XFCJLTPKCPNBQV-BHYUYDJESA-J
form
powder
composition
Dye content, 90%
reaction suitability
core: porphyrin, reaction type: Photocatalysis, reagent type: catalyst
Quality Level
Related Categories
1 of 4
This Item | |||
|---|---|---|---|
| reaction suitability core: porphyrin, reagent type: catalyst, reaction type: Photocatalysis | reaction suitability core: porphyrin, reagent type: catalyst | reaction suitability core: porphyrin, reagent type: catalyst | reaction suitability core: porphyrin, reagent type: catalyst |
| form powder | form solid | form - | form solid |
| Quality Level 100 | Quality Level 100 | Quality Level 100 | Quality Level 100 |
| composition Dye content, 90% | composition - | composition - | composition - |
Application
Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
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Izabela Hanyz et al.
Photochemical & photobiological sciences : Official journal of the European Photochemistry Association and the European Society for Photobiology, 1(2), 126-132 (2003-03-28)
We have studied the influence of solvent acidity on the aggregation/protonation behaviour of two charged tetraphenylporphyrins: positively charged tetrakis(N,N,N-trimethylanilinium-4-yl)porphyrin (TAP) and negatively charged tetrakis(4-sulfonatophenyl)porphyrin (TPPS4). Spectroscopic measurements (absorption, fluorescence, excitation and photoacoustic) have been made to follow the radiative and
T Makino
Clinica chimica acta; international journal of clinical chemistry, 282(1-2), 65-76 (1999-05-26)
A direct colorimetric method is presented for simple and sensitive determination of serum zinc in 0.05-ml samples, using a cationic porphyrin, alpha,beta,gamma,delta-tetrakis(4-N-trimethylaminophenyl) porphine tetratoluenesulfonate salt (ttmapp, epsilon = 41.5 x 10(4) l/mol per cm at 421 nm). 7-Iodo-8-hydroxyquinoline-5-sulfonic acid (Ferron)
Detection of porphyrin using a short peptide immobilized on a surface plasmon resonance sensor chip.
C Nakamura et al.
Biosensors & bioelectronics, 16(9-12), 1095-1100 (2001-10-27)
In this paper the development and feasibility of a novel detection system for a low molecular weight chemical, in which a peptide was utilized as a binding molecule, are described. Surface plasmon resonance (SPR) apparatus was used as a transducer.
A S Kamiguti et al.
Toxicon : official journal of the International Society on Toxinology, 29(8), 961-972 (1991-01-01)
Thirty-four patients envenomed by Bothrops jararaca in Brazil were studied. Of these, 20 (59%) had incoagulable blood associated with local and/or systemic bleeding and 10 of the 20 were thrombocytopenic. Among 14 patients with coagulable blood, 6 (43%) had bleeding
T Makino et al.
Clinica chimica acta; international journal of clinical chemistry, 111(1), 1-8 (1981-03-19)
A colorimetric method is presented for the accurate determination of serum copper in 0.1 ml sized samples, using alpha, beta, gamma, delta-tetrakis(4-N-trimethylaminophenyl)porphine. This new reagent has high sensitivity (epsilon 433nm = 5.1 X 10(5) l.mol--1.cm--1), it is water-soluble and has
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