307254

Sigma-Aldrich

Diisopropylphosphoramidous dichloride

95%

Synonym(s):
(Diisopropylamino)dichlorophosphine, Dichloro(diisopropylamido)phosphorus, Bis(isopropyl)aminodichlorophosphine, Dichloro(diisopropylamino)phosphine
Linear Formula:
(CH3)2CH2NPCl2
CAS Number:
Molecular Weight:
202.06
MDL number:
PubChem Substance ID:
Pricing and availability is not currently available.

Quality Level

assay

95%

reaction suitability

reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand

refractive index

n20/D 1.485 (lit.)

density

1.096 g/mL at 25 °C (lit.)

functional group

phosphine

storage temp.

2-8°C

SMILES string

CC(C)N(C(C)C)P(Cl)Cl

InChI

1S/C6H14Cl2NP/c1-5(2)9(6(3)4)10(7)8/h5-6H,1-4H3

InChI key

UPPVRFOGRCBSJP-UHFFFAOYSA-N

Application

Reagent for the synthesis of peptides and oligonucleotide analogues.

Packaging

5 g in glass bottle

Pictograms

FlameCorrosion

Signal Word

Danger

Hazard Statements

Supp Hazards

EUH001 - EUH014

Personal Protective Equipment

dust mask type N95 (US),Eyeshields,Gloves

Hazard Codes

E,C

Risk Statement

1-5-14-34

Safety Statement

15-26-27-36/37/39-45

RIDADR

UN 2845 4.2

WGK Germany

WGK 3

Flash Point(F)

150.8 °F - closed cup

Flash Point(C)

66 °C - closed cup

The Journal of Organic Chemistry, 59, 6687-6687 (1994)
Tetrahedron, 47, 2449-2449 (1991)

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