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317365

Tetramethylammonium triacetoxyborohydride

95%

Synonym(s):

triacetoxyboranuide

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About This Item

Linear Formula:
(CH3)4N(CH3CO2)3BH
CAS Number:
109704-53-2
Molecular Weight:
263.10
UNSPSC Code:
12352116
NACRES:
NA.22
PubChem Substance ID:
24859075
MDL number:
MFCD00012196
Beilstein/REAXYS Number:
8238791
Assay:
95%
Form:
solid

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Quality Level

100

InChI

1S/C6H10BO6.C4H12N/c1-4(8)11-7(12-5(2)9)13-6(3)10;1-5(2,3)4/h7H,1-3H3;1-4H3/q-1;+1

SMILES string

C[N+](C)(C)C.CC(=O)O[BH-](OC(C)=O)OC(C)=O

InChI key

LCFZZOGKVOTFPU-UHFFFAOYSA-N

assay

95%

form

solid

reaction suitability

reagent type: reductant

mp

93-98 °C (lit.)

functional group

amine

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1 of 4

This Item
86600316393156159
Tetramethylammonium triacetoxyborohydride 95%

Sigma-Aldrich

317365

Tetramethylammonium triacetoxyborohydride

Tetraethylammonium borohydride technical, ≥95% (T)

Sigma-Aldrich

86600

Tetraethylammonium borohydride

Sodium triacetoxyborohydride >95%

Sigma-Aldrich

316393

Sodium triacetoxyborohydride

Sodium cyanoborohydride reagent grade, 95%

Sigma-Aldrich

156159

Sodium cyanoborohydride

assay

95%

assay

≥95% (T)

assay

97%

assay

95%

Quality Level

100

Quality Level

-

Quality Level

200

Quality Level

300

reaction suitability

reagent type: reductant

reaction suitability

reagent type: reductant

reaction suitability

reagent type: reductant

reaction suitability

reagent type: reductant

form

solid

form

crystals

form

-

form

powder

mp

93-98 °C (lit.)

mp

>230 °C

mp

116-120 °C (dec.) (lit.)

mp

>242 °C (dec.) (lit.)

functional group

amine

functional group

amine

functional group

-

functional group

-

Application

Selective reducing agent.[1][2][3]

pictograms

FlameExclamation mark
GHS02,GHS07

signalword

Danger

target_organs

Respiratory system

Storage Class

4.3 - Hazardous materials which set free flammable gases upon contact with water

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type P3 (EN 143) respirator cartridges

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3 - Water-react. 2

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Certificates of Analysis (COA)

Lot/Batch Number
SHBQ7275
SHBM3162
SHBM7450
SHBL5845
SHBH1515V

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Tetrahedron Letters, 44, 7239-7243 (2003)
Ning Shangguan et al.
Organic letters, 9(6), 1093-1096 (2007-02-27)
A formal synthesis of psymberin (irciniastatin A) is presented. Notable features of the synthesis include the chemo-, regio-, and stereoselective oxidation of a 1,3-disubstituted allene, a configuration-dependent spirodiepoxide opening, the efficient syntheses of functionalized trans-2,6-disubstituted pyrans, and the union of
Chemtracts, 5, 188-192 (1992)

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