326348

Sigma-Aldrich

Iron(III) perchlorate hydrate

crystalline, low chloride

Synonym(s):
Perchloric acid iron(III) salt hydrate
Linear Formula:
Fe(ClO4)3 · xH2O
CAS Number:
Molecular Weight:
354.20 (anhydrous basis)
EC Number:
MDL number:
PubChem Substance ID:
NACRES:
NA.22
Pricing and availability is not currently available.

Quality Level

form

crystalline

impurities

<0.005% chloride

color

pale violet

SMILES string

Fe+3.HOH.O-Cl(=O)(=O)=O.O-Cl(=O)(=O)=O.O-Cl(=O)(=O)=O

InChI

1S/3ClHO4.Fe.H2O/c3*2-1(3,4)5;;/h3*(H,2,3,4,5);;1H2/q;;;+3;/p-3

InChI key

PFPIMAZLJXJVAN-UHFFFAOYSA-K

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Application

Catalyst for synthesis of:
  • Fullerene-fused lactones
  • α-Carbonyl furans via one-pot cyclization
  • Fullerodioxolanes via heterocyclization
  • Dialylated indoles via double alkylation
  • Aryl esters via oxidative esterification

Used as chemical actinometer based on photolysis of ferrioxalate in presence of polyoxometalate in aqueous solution

Oxidant for conducting polymer nanoparticles synthesized in ionic liquid by chemical polymerization
Useful starting material for the synthesis of a tris-salicylate Fe(III) complex having bidentate chelating units which allow two coordination modes.

Packaging

100, 500 g in glass bottle

Pictograms

Flame over circleExclamation mark

Signal Word

Danger

Hazard Statements

Target Organs

Respiratory system

Personal Protective Equipment

dust mask type N95 (US),Eyeshields,Gloves

Hazard Codes

O,Xi

Risk Statement

8-36/37/38

Safety Statement

17-26-27

RIDADR

UN 1481 5.1 / PGII

WGK Germany

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Certificate of Analysis
Certificate of Origin
Structural Characterization of a Tris-salicylate Coordination for Iron(III) with the Tripodal Ligand O-TRENSOX.
Guy Serratrice et al.
Inorganic chemistry, 38(5), 840-841 (2001-10-24)

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