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327638

Sigma-Aldrich

Bromopentacarbonylrhenium(I)

98%

Synonym(s):
Pentacarbonylbromorhenium, Pentacarbonylrhenium bromide, Rhenium(I) pentacarbonyl bromide
Linear Formula:
Re(CO)5Br
CAS Number:
Molecular Weight:
406.16
EC Number:
MDL number:
PubChem Substance ID:
NACRES:
NA.22

Quality Level

assay

98%

reaction suitability

core: rhenium
reagent type: catalyst

SMILES string

Br[Re].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+]

InChI

1S/5CO.BrH.Re/c5*1-2;;/h;;;;;1H;/q;;;;;;+1/p-1

InChI key

NWJBOTGGBYFKEJ-UHFFFAOYSA-M

Application

Used to study π-electron deficient complexes between tricarbonylhalorhenium and diimine ligands[1] and also to prepare [3]-ferrocenophane complexes.[2]
Starting material for rhenium-polypyridine complexes that have potential applications in catalysis and solar energy conversion.
Used to study π-electron deficient complexes between tricarbonylhalorhenium and diimine ligands.

Packaging

1 g in glass bottle

Pictograms

Skull and crossbones

Signal Word

Danger

Hazard Classifications

Acute Tox. 3 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

6.1C - Combustible, acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificate of Analysis

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Certificate of Origin

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