Competitive unimolecular reactions at low pressures. The pyrolysis of cyclobutyl chloride.
King KD, et al.
International Journal of Chemical Kinetics, 11(1), 11-21 (1979)
Robert A Moss et al.
Journal of the American Chemical Society, 126(27), 8466-8476 (2004-07-09)
Fragmentations of cyclopropylmethoxychlorocarbene (6) and cyclobutoxychlorocarbene (10) lead to rearrangments that afford mixtures of cyclopropylmethyl chloride (7), cyclobutyl chloride (8), and 3-butenyl chloride (9). Isotopic substitution studies show that these rearrangments are accompanied by partial exchange of the methylene groups...