335002
Carbonyldihydridotris(triphenylphosphine)ruthenium(II)
Synonym(s):
Dihydridocarbonyltris(triphenylphosphine)ruthenium
About This Item
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Quality Level
reaction suitability
core: ruthenium
reagent type: catalyst
reaction type: C-H Activation
mp
161-163 °C (lit.)
SMILES string
[RuH2].[C-]#[O+].c1ccc(cc1)P(c2ccccc2)c3ccccc3.c4ccc(cc4)P(c5ccccc5)c6ccccc6.c7ccc(cc7)P(c8ccccc8)c9ccccc9
InChI
1S/3C18H15P.CO.Ru.2H/c3*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-2;;;/h3*1-15H;;;;
InChI key
MLIYPCQSOXNTLJ-UHFFFAOYSA-N
1 of 4
This Item | 334995 | 223662 | 335037 |
|---|---|---|---|
| reaction suitability core: ruthenium, reagent type: catalyst | reaction suitability core: ruthenium, reagent type: catalyst | reaction suitability core: ruthenium, reagent type: catalyst | reaction suitability core: ruthenium, reagent type: catalyst |
| Quality Level 100 | Quality Level 100 | Quality Level 100 | Quality Level 100 |
| mp 161-163 °C (lit.) | mp 204-206 °C (dec.) (lit.) | mp - | mp 181-183 °C (lit.) |
Application
- Catalyst for conversion of 1,4-alkynediols into pyrroles
- Catalyst for oxidation of primary alcohols to methyl esters
- Catalyst for rearrangement of oximes to amides
- Catalyst for C-C coupling via directed C-H activation
- Catalyst for enyne cyclization
signalword
Warning
hcodes
Hazard Classifications
Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral
Storage Class
11 - Combustible Solids
wgk_germany
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
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