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336874

Sigma-Aldrich

Allyldiphenylphosphine

95%

Synonym(s):
Diphenyl-2-propenylphosphine, NSC 180819, NSC 616248
Linear Formula:
(C6H5)2PCH2CH=CH2
CAS Number:
Molecular Weight:
226.25
MDL number:
PubChem Substance ID:
NACRES:
NA.22

Quality Level

assay

95%

form

liquid

reaction suitability

reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand

refractive index

n20/D 1.619 (lit.)

bp

194-200 °C/15 mmHg (lit.)

density

1.049 g/mL at 25 °C (lit.)

functional group

phosphine

SMILES string

C=CCP(c1ccccc1)c2ccccc2

InChI

1S/C15H15P/c1-2-13-16(14-9-5-3-6-10-14)15-11-7-4-8-12-15/h2-12H,1,13H2

InChI key

PDDYFPPQDKRJTK-UHFFFAOYSA-N

Application

  • Cocatalyst in palladium catalyzed hydrocarboxylation reactions
  • Cocatalyst in Palladium catalyzed cross-coupling reactions
  • Ligand for hydroformylation catalysts
  • Ligand for the rhenium phosphinoborane pendant Lewis acid-assisted reductive coupling reactions
  • Catalyst precursor for alkene hydroboration

Packaging

2, 10 g in glass bottle

Pictograms

Exclamation mark

Signal Word

Warning

Hazard Statements

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

10 - Combustible liquids

WGK

WGK 3

Flash Point(F)

235.4 °F - closed cup

Flash Point(C)

113 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificate of Analysis

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Certificate of Origin

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