336874

Sigma-Aldrich

Allyldiphenylphosphine

95%

Synonym(s):
NSC 616248, Diphenyl-2-propenylphosphine, NSC 180819
Linear Formula:
(C6H5)2PCH2CH=CH2
CAS Number:
Molecular Weight:
226.25
MDL number:
PubChem Substance ID:
NACRES:
NA.22
Pricing and availability is not currently available.

Quality Level

assay

95%

reaction suitability

reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand

refractive index

n20/D 1.619 (lit.)

bp

194-200 °C/15 mmHg (lit.)

density

1.049 g/mL at 25 °C (lit.)

functional group

phosphine

SMILES string

C=CCP(c1ccccc1)c2ccccc2

InChI

1S/C15H15P/c1-2-13-16(14-9-5-3-6-10-14)15-11-7-4-8-12-15/h2-12H,1,13H2

InChI key

PDDYFPPQDKRJTK-UHFFFAOYSA-N

Application

  • Cocatalyst in palladium catalyzed hydrocarboxylation reactions
  • Cocatalyst in Palladium catalyzed cross-coupling reactions
  • Ligand for hydroformylation catalysts
  • Ligand for the rhenium phosphinoborane pendant Lewis acid-assisted reductive coupling reactions
  • Catalyst precursor for alkene hydroboration

Packaging

2, 10 g in glass bottle

Pictograms

Exclamation mark

Signal Word

Warning

Hazard Statements

Precautionary Statements

Target Organs

Respiratory system

Personal Protective Equipment

dust mask type N95 (US),Eyeshields,Gloves

Hazard Codes

Xi

Risk Statement

36/37/38

Safety Statement

26-27-28-36/37/39

RIDADR

NONH for all modes of transport

WGK Germany

WGK 3

Flash Point(F)

235.4 °F - closed cup

Flash Point(C)

113 °C - closed cup

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