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338370
Pentamethylcyclopentadienylrhodium(III) chloride dimer
97%, solid
Synonym(s):
1,3-Cyclopentadiene, 1,2,3,4,5-pentamethyl-, rhodium complex, Bis(dichloro(pentamethylcyclopentadienyl)rhodium), Bis(pentamethylcyclopentadienylrhodium dichloride), Dichloro(pentamethylcyclopentadienyl)rhodium(II) dimer, Tetrachlorobis(pentamethylcyclopentadienyl)dirhodium
About This Item
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Product Name
Pentamethylcyclopentadienylrhodium(III) chloride dimer, 97%
Quality Level
assay
97%
form
solid
reaction suitability
core: rhodium, reaction type: C-H Activation, reagent type: catalyst
reaction type: C-Mannosylation
SMILES string
Cl[Rh]Cl.Cl[Rh]Cl.C[C]1[C](C)[C](C)[C](C)[C]1C.C[C]2[C](C)[C](C)[C](C)[C]2C
InChI
1S/2C10H15.4ClH.2Rh/c2*1-6-7(2)9(4)10(5)8(6)3;;;;;;/h2*1-5H3;4*1H;;/q;;;;;;2*+2/p-4
InChI key
QNIVKTTWBMFSBR-UHFFFAOYSA-J
1 of 4
This Item | |||
|---|---|---|---|
| assay 97% | assay 96% | assay 98% | assay - |
| reaction suitability core: rhodium, reagent type: catalyst | reaction suitability core: rhodium, reagent type: catalyst | reaction suitability core: rhodium, reaction type: Cross Couplings, reagent type: catalyst | reaction suitability core: rhodium, reaction type: Cross Couplings, reagent type: catalyst |
| form solid | form powder | form crystals | form powder |
| Quality Level 100 | Quality Level 100 | Quality Level 100 | Quality Level 100 |
Application
Catalyst for:
- Oxidative olefination reactions
- C-C bond cleavage of secondary alcohols
- Ortho C-H olefination of phenol derivatives
- Oxidative annulation of pyridines
- Oxidative ortho-acylation of benzamides with aldehydes via direct functionalization of the sp2 C-H bond
- Amidation reactions
- Reductive alkylation reactions
- Oxidative olefination reactions
- C-C bond cleavage of secondary alcohols
- Ortho C-H olefination of phenol derivatives
- Oxidative annulation of pyridines
- Oxidative ortho-acylation of benzamides with aldehydes via direct functionalization of the sp2 C-H bond
- Amidation reactions
- Reductive alkylation reactions
signalword
Warning
hcodes
Hazard Classifications
Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Skin Irrit. 2
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
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Global Trade Item Number
| SKU | GTIN |
|---|---|
| 338370-1G | 04061826662458 |
| 338370-250MG | 04061833482285 |
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How is shipping temperature determined? And how is it related to the product storage temperature?
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Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf
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