If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf
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InChI key
PODBBOVVOGJETB-UHFFFAOYSA-N
InChI
1S/C32H16N8.Zn/c1-2-10-18-17(9-1)25-33-26(18)38-28-21-13-5-6-14-22(21)30(35-28)40-32-24-16-8-7-15-23(24)31(36-32)39-29-20-12-4-3-11-19(20)27(34-29)37-25;/h1-16H;/q-2;+2
SMILES string
[Zn]1n2c3nc4nc(nc5n1c(nc6nc(nc2c7ccccc37)c8ccccc68)c9ccccc59)c%10ccccc4%10
composition
Dye content, 97%
reaction suitability
reagent type: catalyst
core: zinc
λmax
701 nm
orbital energy
HOMO 5.17 eV (CV), LUMO 3.78 eV (CV)
Quality Level
OPV device performance
ITO/ZnPc:P60 (1:1)/Bphen/Ag
- Short-circuit current density (Jsc): 11.7 mA/cm2
- Open-circuit voltage (Voc): 0.54 V
- Fill Factor (FF): 0.62
- Power Conversion Efficiency (PCE): 3.9 %
1 of 4
This Item | |||
|---|---|---|---|
| reaction suitability reagent type: catalyst | reaction suitability - | reaction suitability - | reaction suitability - |
| Quality Level 100 | Quality Level - | Quality Level 100 | Quality Level - |
| composition Dye content, 97% | composition - | composition - | composition Dye content, 70% |
| λmax 701 nm | λmax 736 nm | λmax 727 nm | λmax 658 nm |
| orbital energy HOMO 5.17 eV (CV) | orbital energy - | orbital energy - | orbital energy - |
| OPV device performance ITO/ZnPc:P60 (1:1)/Bphen/Ag
| OPV device performance - | OPV device performance - | OPV device performance - |
General description
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
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While dye sensitization as the basis for color photography has been accepted for a very long time,1 attempts to use this principle for the conversion of solar light to electricity generally had resulted only in very low photocurrents, below 100 nA/cm
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How can I determine the shelf life / expiration / retest date of this product?
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What is the solubility and in what can it be dissolved?
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The solubility of this product has not tested on a lot-to-lot basis. However, historical data indicates that this material is soluble in pyridine (donor solvent), 1-Chloronaphthalene, Benzene, Dimethylacetamide, 1-Propanol and slightly soluble in water at 0.5%. External sources state that this compound is also slightly soluble in DMSO at < 1 mg/mL and DMF at 2.7 mg/mL (may require sonication and warming).
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How is shipping temperature determined? And how is it related to the product storage temperature?
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Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf
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