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341169

Zinc phthalocyanine

Dye content 97 %

Synonym(s):

Phthalocyanine zinc salt

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5 G

$248.00

25 G

$1,200.00

$248.00


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About This Item

Empirical Formula (Hill Notation):
C32H16N8Zn
CAS Number:
Molecular Weight:
577.91
UNSPSC Code:
12352103
NACRES:
NA.23
PubChem Substance ID:
EC Number:
238-262-5
Beilstein/REAXYS Number:
4121852
MDL number:

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InChI key

PODBBOVVOGJETB-UHFFFAOYSA-N

InChI

1S/C32H16N8.Zn/c1-2-10-18-17(9-1)25-33-26(18)38-28-21-13-5-6-14-22(21)30(35-28)40-32-24-16-8-7-15-23(24)31(36-32)39-29-20-12-4-3-11-19(20)27(34-29)37-25;/h1-16H;/q-2;+2

SMILES string

[Zn]1n2c3nc4nc(nc5n1c(nc6nc(nc2c7ccccc37)c8ccccc68)c9ccccc59)c%10ccccc4%10

composition

Dye content, 97%

reaction suitability

reagent type: catalyst
core: zinc

λmax

701 nm

orbital energy

HOMO 5.17 eV (CV), LUMO 3.78 eV (CV)

Quality Level

OPV device performance

ITO/ZnPc:P60 (1:1)/Bphen/Ag

  • Short-circuit current density (Jsc): 11.7 mA/cm2
  • Open-circuit voltage (Voc): 0.54 V
  • Fill Factor (FF): 0.62
  • Power Conversion Efficiency (PCE): 3.9 %

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1 of 4

This Item
383813379557362549
reaction suitability

reagent type: catalyst
core: zinc

reaction suitability

-

reaction suitability

-

reaction suitability

-

Quality Level

100

Quality Level

-

Quality Level

100

Quality Level

-

composition

Dye content, 97%

composition

-

composition

-

composition

Dye content, 70%

λmax

701 nm

λmax

736 nm

λmax

727 nm

λmax

658 nm

orbital energy

HOMO 5.17 eV (CV)

orbital energy

-

orbital energy

-

orbital energy

-

OPV device performance

ITO/ZnPc:P60 (1:1)/Bphen/Ag

  • Short-circuit current density (Jsc): 11.7 mA/cm2
  • Open-circuit voltage (Voc): 0.54 V
  • Fill Factor (FF): 0.62
  • Power Conversion Efficiency (PCE): 3.9 %

OPV device performance

-

OPV device performance

-

OPV device performance

-

General description

Zinc (II) phthalocyanine (ZnPc) complexes show photosensitizing properties. Phthalocyanines show significant Π−Π interactions and easy formation of H aggregates.[1]

Application

Zinc phthalocyanine finds general applications in industry (catalysts, photoconductors etc) and biomedical (photodynamic therapy, PDT).[2] ZnPc may be used to photooxidise cyclohexane.[3] A study reports functionalization of polymer membrane with ZnPc.[4]

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)


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I M Tynga et al.
Journal of photochemistry and photobiology. B, Biology, 120, 171-176 (2012-12-26)
The development of curative techniques which are selective for neoplasms is one of the main focal areas in cancer research. The mechanism of cell damage due to Zinc phthalocyanine (ZnPcSmix)-mediated photodynamic therapy (PDT) in a breast cancer cell line (MCF-7)
Polyamide nanofiber membranes functionalized with zinc phthalocyanines.
Goethals A, et al.
Journal of Applied Polymer Science, 131(13) (2014)
Characterization of ITO/CuPc/Al and ITO/ZnPc/Al structures using optical and capacitance spectroscopy
Reis, F. T.; et al.
Synthetic Metals, 138, 33-37 (2003)
Zinc phthalocyanine photocatalyzed oxidation of cyclohexene.
Sehlotho N and Nyokong T
J. Mol. Catal. A: Chem., 219(2), 201-207 (2004)
Jiangtao Ren et al.
Biosensors & bioelectronics, 35(1), 401-406 (2012-04-10)
In this work, a simple and label-free fluorescent method via fluorescent indicator displacement (FID) was proposed for enantioselectively determining d-enantiomer of arginine vasopressin (DV) using DV-specific DNA aptamer (V-apt) and one guanidiniophthalocyanine dye (Zn-DIGP). Zn-DIGP that preferentially binds to single-stranded

Articles

Single-walled carbon nanohorns(SWCNHs) - Find manufacturing, material properties, and applications of carbon nanohorns.

While dye sensitization as the basis for color photography has been accepted for a very long time,1 attempts to use this principle for the conversion of solar light to electricity generally had resulted only in very low photocurrents, below 100 nA/cm

Questions

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  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

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  2. What is the solubility and in what can it be dissolved?

    1 answer
    1. The solubility of this product has not tested on a lot-to-lot basis. However, historical data indicates that this material is soluble in pyridine (donor solvent), 1-Chloronaphthalene, Benzene, Dimethylacetamide, 1-Propanol and slightly soluble in water at 0.5%. External sources state that this compound is also slightly soluble in DMSO at < 1 mg/mL and DMF at 2.7 mg/mL (may require sonication and warming).

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  3. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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