If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf
341622
Bromopentacarbonylmanganese(I)
98%
Synonym(s):
Bromopentacarbonylmanganese(I), Manganese pentacarbonyl bromide
Select a Size
| Pack Size | SKU | Availability | Price |
|---|---|---|---|
| 5 g | Available to ship TODAYfromMILWAUKEE | $322.00 |
About This Item
Quality Level
assay
98%
form
powder or crystals
reaction suitability
core: manganese, reagent type: catalyst
storage temp.
2-8°C
SMILES string
[Mn]Br.[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+]
InChI
1S/5CO.BrH.Mn/c5*1-2;;/h;;;;;1H;/q;;;;;;+1/p-1
InChI key
OESORJHGSXJTKX-UHFFFAOYSA-M
General description
Application
- A precursor to synthesize manganese complex, [Mn(CO)5H], which was then used as a catalyst in the reduction of levulinic acid (LA) to methyltetrahydrofuran (MTHF) and the reductive amination of LA to N-substituted pyrrolidines.
- A precursor to prepare Mn(I) complexes bearing bifunctional ligands, which are used as catalysts for the transfer-hydrogenation of various ketones and imines using 2-propanol as the hydrogen donor.
- A catalyst in the selective C2-H activation reactions.
1 of 1
This Item | |||
|---|---|---|---|
| assay 98% | assay 98% | assay 98% | assay 98% |
| form powder or crystals | form powder or crystals | form powder | form crystalline |
| storage temp. 2-8°C | storage temp. 2-8°C | storage temp. - | storage temp. - |
| Quality Level 100 | Quality Level 100 | Quality Level 200 | Quality Level 100 |
| reaction suitability core: manganese, reagent type: catalyst | reaction suitability core: manganese, reagent type: catalyst | reaction suitability core: magnesium | reaction suitability core: manganese |
signalword
Warning
hcodes
Hazard Classifications
Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
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Global Trade Item Number
| SKU | GTIN |
|---|---|
| 341622-5G | 04061826754290 |
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How can I determine the shelf life / expiration / retest date of this product?
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How is shipping temperature determined? And how is it related to the product storage temperature?
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Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf
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