![Dichlorotriphenylphosphine[bis(2-(ethylthio)ethyl)amine]ruthenium(II) 97%](/deepweb/assets/sigmaaldrich/product/structures/355/871/c9ac8b63-9a77-4c66-b545-cb7c41673aa4/640/c9ac8b63-9a77-4c66-b545-cb7c41673aa4.png)
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343706
Dichloro(p-cymene)ruthenium(II) dimer
Synonym(s):
(p-Cymene)ruthenium(II) chloride dimer, Benzene, 1-methyl-4-(1-methylethyl)-, ruthenium complex
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$81.30
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InChI
1S/2C10H14.4ClH.2Ru/c2*1-8(2)10-6-4-9(3)5-7-10;;;;;;/h2*4-8H,1-3H3;4*1H;;/q;;;;;;2*+2/p-4
SMILES string
Cl[Ru]Cl.Cl[Ru]Cl.CC(C)c1ccc(C)cc1.CC(C)c2ccc(C)cc2
InChI key
LAXRNWSASWOFOT-UHFFFAOYSA-J
reaction suitability
core: ruthenium, reagent type: catalyst
reaction type: C-H Activation
greener alternative product characteristics
Catalysis
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mp
247.0-250.0 °C (dec.) (lit.)
greener alternative category
, Aligned
Quality Level
1 of 4
This Item | 337331 | 746339 | 661023 |
|---|---|---|---|
| reaction suitability core: ruthenium, reagent type: catalyst | reaction suitability core: ruthenium, reaction type: solution phase peptide synthesis, reagent type: catalyst | reaction suitability core: ruthenium, reagent type: catalyst | reaction suitability core: rhodium, reagent type: catalyst |
| Quality Level 100 | Quality Level - | Quality Level 100 | Quality Level 100 |
| mp 247.0-250.0 °C (dec.) (lit.) | mp - | mp 300-310 °C | mp 199 °C (dec.) |
| greener alternative product characteristics Catalysis | greener alternative product characteristics Catalysis | greener alternative product characteristics Catalysis | greener alternative product characteristics Catalysis |
| sustainability Greener Alternative Product | sustainability Greener Alternative Product | sustainability Greener Alternative Product | sustainability Greener Alternative Product |
| greener alternative category , Aligned | greener alternative category , Aligned | greener alternative category | greener alternative category |
General description
Dichloro(p-cymene)ruthenium(II) dimer is a saturated 18-electron complex used as a starting material for the synthesis of organometallic complexes.[1]
Application
A Practical and Benign Synthesis of Primary Amines through Ruthenium-Catalyzed Reduction of Nitriles
Ruthenium-Catalyzed N-Alkylation of Amines and Sulfonamides Using Borrowing Hydrogen Methodology
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Warning
hcodes
Hazard Classifications
Eye Irrit. 2
Storage Class
11 - Combustible Solids
wgk
WGK 2
flash_point_f
Not applicable
flash_point_c
Not applicable
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Trost group's protocol yields α-vinylsilanes from terminal acetylenes using [Cp*Ru(MeCN)3]PF6 catalyst and others for hydrosilylation.
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Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf
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