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345458

Boron trichloride solution

1.0 M in p-xylene

Synonym(s):

Boron chloride, Trichloroborane

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About This Item

Empirical Formula (Hill Notation):
BCl3
CAS Number:
10294-34-5
Molecular Weight:
117.17
NACRES:
NA.22
PubChem Substance ID:
24861323
UNSPSC Code:
12352106
MDL number:
MFCD00011313

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InChI

1S/BCl3/c2-1(3)4

SMILES string

ClB(Cl)Cl

InChI key

FAQYAMRNWDIXMY-UHFFFAOYSA-N

vapor density

4.03 (vs air)

vapor pressure

1 mmHg ( 12.7 °C)

form

liquid

reaction suitability

core: boron, reagent type: Lewis acid, reagent type: catalyst

concentration

1.0 M in p-xylene

density

0.901 g/mL at 25 °C

Quality Level

200

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1 of 4

This Item
91379348325178934
Boron trichloride solution 1.0 M in p-xylene

Sigma-Aldrich

345458

Boron trichloride solution

Boron trichloride solution 12% in methanol, derivatization grade (GC derivatization), LiChropur™

Supelco

91379

Boron trichloride solution

Boron trichloride solution 1.0 M in heptane

Sigma-Aldrich

348325

Boron trichloride solution

Boron trichloride solution 1.0 M in methylene chloride

Sigma-Aldrich

178934

Boron trichloride solution

reaction suitability

core: boron, reagent type: catalyst, reagent type: Lewis acid

reaction suitability

-

reaction suitability

core: boron, reagent type: Lewis acid, reagent type: catalyst

reaction suitability

core: boron, reagent type: Lewis acid, reagent type: catalyst

form

liquid

form

liquid

form

liquid

form

liquid

Quality Level

200

Quality Level

100

Quality Level

100

Quality Level

200

density

0.901 g/mL at 25 °C

density

0.875-0.895 g/mL at 20 °C

density

0.74 g/mL at 25 °C

density

1.326 g/mL at 25 °C

vapor density

4.03 (vs air)

vapor density

-

vapor density

-

vapor density

-

vapor pressure

1 mmHg ( 12.7 °C)

vapor pressure

-

vapor pressure

-

vapor pressure

29.72 psi ( 55 °C), 9.05 psi ( 20 °C)

Application

For preparing methyl esters of fatty acids and for transesterification of triglycerides.

signalword

Danger

Hazard Classifications

Acute Tox. 2 Oral - Acute Tox. 3 Inhalation - Acute Tox. 4 Dermal - Aquatic Chronic 3 - Asp. Tox. 1 - Eye Dam. 1 - Flam. Liq. 3 - Repr. 1B - Skin Corr. 1B - STOT SE 3

target_organs

Respiratory system

supp_hazards

EUH014

Storage Class

3 - Flammable liquids

wgk

WGK 3

flash_point_f

84.2 °F - closed cup

flash_point_c

29 °C - closed cup

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

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Certificates of Analysis (COA)

Lot/Batch Number
SHBQ8733
SHBD1119V
SHBC1894V
SHBB5940V
SHBB5940

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George W Kabalka et al.
The Journal of organic chemistry, 73(7), 2668-2673 (2008-03-06)
A boron trihalide mediated alkyne-aldehyde coupling reaction leading to stereodefined 1,3,5-triaryl-1,5-dihalo-1,4-pentadienes is described. The study led to the discovery of a direct substitution of hydroxyl groups by stereodefined alkenyl moieties using alkenylboron dihalides. During the investigation, it was also discovered
Lei Zhang et al.
Journal of combinatorial chemistry, 7(4), 622-626 (2005-07-12)
A novel and efficient microwave-assisted, BCl3-mediated coupling reaction to synthesize salicylamide structures from phenols and isocyanates is described.
Coordination compounds of boron trichloride; systems with the propyl chlorides.
D R MARTIN et al.
The Journal of physical and colloid chemistry, 51(2), 425-430 (1947-03-01)
Jayaraman Selvakumar et al.
Organic & biomolecular chemistry, 8(18), 4056-4058 (2010-07-29)
Isoindoloisoquinalinone, pyrroloisoquinolinone and benzo[a]quinolizinone units are constructed via intramolecular cyclization of the methoxy substituted N-phenethylimides using BBr(3).
Juan Xie et al.
Carbohydrate research, 340(3), 481-487 (2005-02-01)
Boron trichloride has been found to promote selective deprotection of 1,2- or 1,3-cis oriented secondary benzyl ethers of per-benzylated C-glycosyl derivatives. The reactivity towards BCl(3) follows the order: C-4>or=C-2>C-6>C-3 for C-glucopyranosyl derivatives and C-3>or=C-4>C-6>C-2 for C-galactopyranosyl derivatives. Preparatively useful selective
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