345458

Sigma-Aldrich

Boron trichloride solution

1.0 M in p-xylene

Empirical Formula (Hill Notation):
BCl3
CAS Number:
Molecular Weight:
117.17
MDL number:
PubChem Substance ID:
NACRES:
NA.22
Pricing and availability is not currently available.

vapor density

4.03 (vs air)

Quality Level

vapor pressure

1 mmHg ( 12.7 °C)

reaction suitability

core: boron
reagent type: Lewis acid
reagent type: catalyst

concentration

1.0 M in p-xylene

density

0.901 g/mL at 25 °C

SMILES string

ClB(Cl)Cl

InChI

1S/BCl3/c2-1(3)4

InChI key

FAQYAMRNWDIXMY-UHFFFAOYSA-N

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Related Categories

Packaging

100, 800 mL in Sure/Seal™

Application

For preparing methyl esters of fatty acids and for transesterification of triglycerides.

Signal Word

Danger

Supp Hazards

EUH014

Personal Protective Equipment

dust mask type N95 (US),Eyeshields,Gloves

RIDADR

UN 2920 3(8) / PGII

WGK Germany

WGK 3

Flash Point(F)

84.2 °F - closed cup

Flash Point(C)

29 °C - closed cup

Certificate of Analysis
Certificate of Origin
Jayaraman Selvakumar et al.
Organic & biomolecular chemistry, 8(18), 4056-4058 (2010-07-29)
Isoindoloisoquinalinone, pyrroloisoquinolinone and benzo[a]quinolizinone units are constructed via intramolecular cyclization of the methoxy substituted N-phenethylimides using BBr(3).
Lei Zhang et al.
Journal of combinatorial chemistry, 7(4), 622-626 (2005-07-12)
A novel and efficient microwave-assisted, BCl3-mediated coupling reaction to synthesize salicylamide structures from phenols and isocyanates is described.
Juan Xie et al.
Carbohydrate research, 340(3), 481-487 (2005-02-01)
Boron trichloride has been found to promote selective deprotection of 1,2- or 1,3-cis oriented secondary benzyl ethers of per-benzylated C-glycosyl derivatives. The reactivity towards BCl(3) follows the order: C-4>or=C-2>C-6>C-3 for C-glucopyranosyl derivatives and C-3>or=C-4>C-6>C-2 for C-galactopyranosyl derivatives. Preparatively useful selective...
George W Kabalka et al.
The Journal of organic chemistry, 73(7), 2668-2673 (2008-03-06)
A boron trihalide mediated alkyne-aldehyde coupling reaction leading to stereodefined 1,3,5-triaryl-1,5-dihalo-1,4-pentadienes is described. The study led to the discovery of a direct substitution of hydroxyl groups by stereodefined alkenyl moieties using alkenylboron dihalides. During the investigation, it was also discovered...
C Matthäus et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 57(3), 521-534 (2001-04-13)
A method for expressing quantitatively the vibrational normal modes of a molecule in a basis set consisting of the normal vibrations (plus translations and rotations) of its constituent fragments is presented. The method is illustrated by describing the vibrational modes...

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