346160
Ethynylmagnesium chloride solution
0.5 M in THF
Synonym(s):
Chloromagnesium acetylide
About This Item
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InChI
1S/C2H.ClH.Mg/c1-2;;/h1H;1H;/q;;+1/p-1
SMILES string
Cl[Mg]C#C
InChI key
YEWNLGTVYUADOR-UHFFFAOYSA-M
form
liquid
reaction suitability
reaction type: Grignard Reaction
concentration
0.5 M in THF
density
0.921 g/mL at 25 °C
storage temp.
2-8°C
Quality Level
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Related Categories
1 of 4
This Item | 346152 | 562157 | 562211 |
|---|---|---|---|
| reaction suitability reaction type: Grignard Reaction | reaction suitability reaction type: Grignard Reaction | reaction suitability reaction type: Grignard Reaction | reaction suitability reaction type: Grignard Reaction |
| Quality Level 100 | Quality Level 200 | Quality Level 100 | Quality Level 100 |
| concentration 0.5 M in THF | concentration 0.5 M in THF | concentration 0.5 M in THF | concentration 0.5 M in THF |
| density 0.921 g/mL at 25 °C | density 0.94 g/mL at 25 °C | density 0.923 g/mL at 25 °C | density 0.951 g/mL at 25 °C |
| storage temp. 2-8°C | storage temp. 2-8°C | storage temp. 2-8°C | storage temp. 2-8°C |
| form liquid | form - | form - | form - |
Application
- To synthesize 1-ethynyldeoxyribose derivatives which can further undergo Sonogashira coupling with various aryl, heteroaryl, and metallocenyl derivatives.[1]
- In one of the key synthetic steps of substituted naphthostyrils.[2]
- In the preparation of propargylic ester precursor for the synthesis of 1,3-dienylphosphonates.[3]
related product
signalword
Danger
Hazard Classifications
Acute Tox. 4 Oral - Carc. 2 - Eye Irrit. 2 - Flam. Liq. 2 - STOT SE 3
target_organs
Central nervous system, Respiratory system
supp_hazards
Storage Class
4.3 - Hazardous materials which set free flammable gases upon contact with water
wgk
WGK 3
flash_point_f
-16.6 °F - closed cup
flash_point_c
-27 °C - closed cup
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