346187

Sigma-Aldrich

Trioctylphosphine oxide

technical grade, 90%

Synonym(s):
(Oct)3PO, TOPO®
Linear Formula:
[CH3(CH2)7]3PO
CAS Number:
Molecular Weight:
386.63
Beilstein/REAXYS Number:
1796648
EC Number:
MDL number:
PubChem Substance ID:
NACRES:
NA.22

grade

technical grade

Quality Level

assay

90%

reaction suitability

reagent type: ligand

bp

201-202 °C/2 mmHg (lit.)

mp

50-52 °C (lit.)

functional group

phosphine

SMILES string

CCCCCCCCP(=O)(CCCCCCCC)CCCCCCCC

InChI

1S/C24H51OP/c1-4-7-10-13-16-19-22-26(25,23-20-17-14-11-8-5-2)24-21-18-15-12-9-6-3/h4-24H2,1-3H3

InChI key

ZMBHCYHQLYEYDV-UHFFFAOYSA-N

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Packaging

100, 500 g in glass bottle

Application

Used as an extraction or stabilizing agent; also useful as a capping ligand for the production of quantum dots such as CdSe.

Legal Information

TOPO is a registered trademark of Life Technologies

Pictograms

Corrosion

Signal Word

Danger

Hazard Statements

Precautionary Statements

Personal Protective Equipment

dust mask type N95 (US),Eyeshields,Gloves

RIDADR

NONH for all modes of transport

WGK Germany

WGK 2

Flash Point(F)

230.0 °F - closed cup

Flash Point(C)

110 °C - closed cup

Certificate of Analysis

Certificate of Origin

Aditya Sharma et al.
Analytical chemistry, 84(7), 3082-3089 (2012-03-03)
We present results of the studies relating to preparation of Langmuir-Blodgett (LB) monolayers of tri-n-octylphosphine oxide-capped cadmium selenide quantum dots (QCdSe) onto indium-tin oxide (ITO) coated glass substrate. The monolayer behavior has been studied at the air-water interface under various...
Jungkon Kim et al.
Aquatic toxicology (Amsterdam, Netherlands), 97(2), 116-124 (2010-01-20)
The potential ecotoxicological consequences about semiconductor crystal nanoparticles (NPs) are a growing concern. However, our understanding of the mechanism of toxicity in NPs is very limited, especially under varying environmental conditions such as ultraviolet (UV) light. We performed an in...
Yong Tao et al.
Journal of chromatography. A, 1216(35), 6259-6266 (2009-07-28)
By using ionic liquid as membrane liquid and tri-n-octylphosphine oxide (TOPO) as additive, hollow fiber supported liquid phase microextraction (HF-LPME) was developed for the determination of five sulfonamides in environmental water samples by high-performance liquid chromatography with ultraviolet detection The...
Harikrishna Bavireddi et al.
The Analyst, 137(21), 5123-5127 (2012-09-25)
Highly fluorescent water soluble glyco-quantum dots were synthesized using a sonochemical procedure. The synthetic approach is based on specific host-guest interactions between β-cyclodextrin (β-CD) and trioctylphosphine oxide (TOPO) surfactant on quantum dots. The modified QDs were analyzed by a combination...
Sanjeev Kumar Mahto et al.
Toxicology in vitro : an international journal published in association with BIBRA, 24(4), 1070-1077 (2010-04-07)
With the widespread use of quantum dots (QDs), the likelihood of exposure to QDs has been assumed to have increased substantially. Recently, QDs have been employed in numerous biological and medical applications. However, there is a lack of toxicological data...

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