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357634

Sigma-Aldrich

Nickel

≥99.9%, wire, diam. 0.25 mm

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About This Item

Empirical Formula (Hill Notation):
Ni
CAS Number:
Molecular Weight:
58.69
EC Number:
MDL number:
UNSPSC Code:
11101706
PubChem Substance ID:
NACRES:
NA.22

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Product Name

Nickel, wire, diam. 0.25 mm, ≥99.9%

Quality Level

assay

≥99.9%

form

wire

reaction suitability

core: nickel
reagent type: catalyst

resistivity

6.97 μΩ-cm, 20°C

diam.

0.25 mm

bp

2732 °C (lit.)

mp

1453 °C (lit.)

density

8.9 g/mL at 25 °C (lit.)

SMILES string

[Ni]

InChI

1S/Ni

InChI key

PXHVJJICTQNCMI-UHFFFAOYSA-N

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This Item
268259767484267058
assay

≥99.9%

assay

≥99.9%

assay

99.95% trace metals basis

assay

≥99.99% trace metals basis

reaction suitability

core: nickel, reagent type: catalyst

reaction suitability

core: nickel, reagent type: catalyst

reaction suitability

core: nickel

reaction suitability

-

form

wire

form

foil

form

solid

form

wire

Quality Level

100

Quality Level

100

Quality Level

100

Quality Level

100

bp

2732 °C (lit.)

bp

2732 °C (lit.)

bp

2732 °C (lit.)

bp

2732 °C (lit.)

mp

1453 °C (lit.)

mp

1453 °C (lit.)

mp

1453 °C (lit.)

mp

1453 °C (lit.)

Application

Nickel can be used as a catalyst in:
  • Various reactions such as hydrogenation, oxidative addition, C−H activation, oxidative cyclization, cross-coupling reaction.[1]
  • Selective hydrogenolysis of the aromatic ethers.[2]
  • Steam reforming process to produce hydrogen and synthesis gas.[3]
  • Benzaldehyde hydrogenation.[4]
  • Methanation of CO2.[5]

Preparation Note

5 m (approximately 2.2 g)

pictograms

Health hazardExclamation mark

signalword

Danger

Hazard Classifications

Carc. 2 - Skin Sens. 1 - STOT RE 1

Storage Class

6.1D - Non-combustible acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects

wgk_germany

WGK 1

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges


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Benzaldehyde hydrogenation over supported nickel catalysts.
Saadi A, et al.
J. Mol. Catal. A: Chem., 253(1-2), 79-85 (2006)
Four challenges for nickel steam-reforming catalysts.
Sehested J
Catalysis Today, 111(1-2), 103-110 (2006)
Mesoporous nickel catalyst supported on multi-walled carbon nanotubes for carbon dioxide methanation.
Wang W, et al.
International Journal of Hydrogen Energy, 41(2), 967-975 (2016)
Alexey G Sergeev et al.
Science (New York, N.Y.), 332(6028), 439-443 (2011-04-23)
Selective hydrogenolysis of the aromatic carbon-oxygen (C-O) bonds in aryl ethers is an unsolved synthetic problem important for the generation of fuels and chemical feedstocks from biomass and for the liquefaction of coal. Currently, the hydrogenolysis of aromatic C-O bonds
Ornella Valenti et al.
Cerebral cortex (New York, N.Y. : 1991), 19(3), 658-674 (2008-07-18)
The prefrontal cortex receives multiple inputs from the hippocampal complex, which are thought to drive memory-guided behavior. Moreover, dysfunctions of both regions have been repeatedly associated with several psychiatric disorders. Therefore, understanding the interconnections and modulatory interactions between these regions

Questions

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  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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