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360155

Sigma-Aldrich

Bis(salicylideniminato-3-propyl)methylaminocobalt(II)

97%

Synonym(s):
[[2,2′-[(Methylimino-κN)bis[3,1-propanediyl(nitrilo-κN)methylidyne]]bis[phenolato-κO]](2-)]cobalt, [[α,α′-[(Methylimino)bis(trimethylenenitrilo)]di-o-cresolato](2-)]cobalt
Linear Formula:
CH3N[(CH2)3N=CHC6H4-2-(O)]2Co
CAS Number:
Molecular Weight:
410.38
MDL number:
PubChem Substance ID:
NACRES:
NA.22

Quality Level

assay

97%

reaction suitability

core: cobalt
reagent type: catalyst

mp

290-292 °C (lit.)

SMILES string

CN1CCC\N=C\c2ccccc2O[Co]Oc3ccccc3\C=N\CCC1

InChI

1S/C21H27N3O2.Co/c1-24(14-6-12-22-16-18-8-2-4-10-20(18)25)15-7-13-23-17-19-9-3-5-11-21(19)26;/h2-5,8-11,16-17,25-26H,6-7,12-15H2,1H3;/q;+2/p-2/b22-16+,23-17+;

InChI key

BJSFADUIUGJFKX-VLQAMQNLSA-L

Application

Catalyst for:
  • Biomimetic coupled catalytic system
  • Cobalt-Schiff base complex catalyzed oxidation of para-substituted phenolics
  • Allylation, oxidation, and oxidative cleavages
  • Oxidative carbonylation of phenol

Packaging

5 g in glass bottle

Certificate of Analysis

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Certificate of Origin

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