If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf
364649
tert-Butylmagnesium chloride solution
1.0 M in THF
Synonym(s):
t-Butylmagnesium chloride, tert-Butylchloromagnesium, Chloro(1,1-dimethylethyl)magnesium
Select a Size
| Pack Size | SKU | Availability | Price |
|---|---|---|---|
| 100 mL | Available to ship TODAYfromMILWAUKEE | $80.90 | |
| 4 x 25 mL | Available to ship TODAYfromMILWAUKEE | $115.00 | |
| 800 mL | Available to ship TODAYfromMILWAUKEE | $335.00 |
About This Item
$80.90
Available to ship TODAYDetails
Quality Level
reaction suitability
reaction type: Grignard Reaction
packaging
Sure/Seal™ of
concentration
1.0 M in THF
density
0.931 g/mL at 25 °C
SMILES string
CC(C)(C)[Mg]Cl
InChI
1S/C4H9.ClH.Mg/c1-4(2)3;;/h1-3H3;1H;/q;;+1/p-1
InChI key
ZDRJSYVHDMFHSC-UHFFFAOYSA-M
General description
Application
It can be used in:
- Grignard metathesis reaction of 2,5-dibromo-3-hexylthiophene to form 2-bromo-5-magnesiobromo-3-hexylthiophene.
- A key step for the asymmetric synthesis of sulfinyl transfer agents using cinchona alkaloids quinine and quinidine as chiral auxiliaries.
Other Notes
Legal Information
1 of 1
This Item | |||
|---|---|---|---|
| concentration 1.0 M in THF | concentration 2.0 M in diethyl ether | concentration 1.0 M in THF | concentration 0.5 M in THF |
| Quality Level 200 | Quality Level 200 | Quality Level 100 | Quality Level 100 |
| density 0.931 g/mL at 25 °C | density 0.828 g/mL at 25 °C | density 0.952 g/mL at 25 °C | density 0.906 g/mL at 25 °C |
| reaction suitability reaction type: Grignard Reaction | reaction suitability reaction type: Grignard Reaction | reaction suitability reaction type: Grignard Reaction | reaction suitability reaction type: Grignard Reaction |
| packaging Sure/Seal™ of | packaging Sure/Seal™ of | packaging Sure/Seal™ of | packaging Sure/Seal™ of |
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signalword
Danger
target_organs
Central nervous system, Respiratory system
supp_hazards
Storage Class
4.2 - Pyrophoric and self-heating hazardous materials
flash_point_f
1.4 °F - closed cup
flash_point_c
-17 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
Hazard Classifications
Acute Tox. 4 Oral - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Pyr. Liq. 1 - Skin Corr. 1B - STOT SE 3 - Water-react. 1
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Global Trade Item Number
| SKU | GTIN |
|---|---|
| 364649-4X25ML | 04065268447420 |
| 364649-800ML | 04061837797446 |
| 364649-100ML | 04061837797439 |
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How can I determine the shelf life / expiration / retest date of this product?
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How is shipping temperature determined? And how is it related to the product storage temperature?
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Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf
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