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368059

Sigma-Aldrich

Sodium bis(trimethylsilyl)amide solution

0.6 M in toluene

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Synonym(s):
Hexamethyldisilazane sodium salt solution
Linear Formula:
(CH3)3Si2NNa
CAS Number:
1070-89-9
Molecular Weight:
183.37
Beilstein/REAXYS Number:
3629917
MDL number:
MFCD00009835
PubChem Substance ID:
24862883
NACRES:
NA.22
Pricing and availability is not currently available.

Quality Level

100

concentration

0.6 M in toluene

density

0.87 g/mL at 25 °C

SMILES string

CSi(C)(C)N(Na)Si(C)(C)C

InChI

1S/C6H18NSi2.Na/c1-8(2,3)7-9(4,5)6;/h1-6H3;/q-1;+1

InChI key

WRIKHQLVHPKCJU-UHFFFAOYSA-N

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Related Categories

Signal Word

Danger

Target Organs

Central nervous system

Supp Hazards

EUH014

Personal Protective Equipment

dust mask type N95 (US),Eyeshields,Gloves

Hazard Codes

F,C

Risk Statement

63-11-14-34-48/20-65-67

Safety Statement

16-26-36/37/39-45-62

RIDADR

UN 2924 8(3) / PGII

WGK Germany

WGK 2

Flash Point(F)

42.8 °F - closed cup

Flash Point(C)

6 °C - closed cup

Jerry Isaacson et al.
Angewandte Chemie (International ed. in English), 48(10), 1845-1848 (2009-01-29)
(-)-Dysibetaine has been synthesized in 11 steps from readily available L-malic acid (see scheme). The key step is a unique Ugi 4-center-3-component cyclization reaction, where an ester group acts as the carboxylic acid component. The use of 1,1,1,3,3,3-hexamethyldisilazane as an...
Marko Marinkovic et al.
Advanced materials (Deerfield Beach, Fla.), 24(29), 4005-4009 (2012-06-26)
A model is presented that describes the gate-voltage-dependent contact resistance and channel-length-dependent charge carrier mobility of small-molecule-based organic thin-film transistors in top and bottom drain/source contact configuration.
Xinfeng Zhang et al.
Langmuir : the ACS journal of surfaces and colloids, 26(22), 16828-16832 (2010-10-06)
Two-dimensional silica nanoparticle assemblies were obtained by deposition of bubble made from a surfactant solution containing nanoparticles onto hydrophobic silicon substrate. The morphologies of the nanoparticle assemblies can be finely controlled by several experimental parameters, including surfactant concentration, nanoparticle concentration...
Adrienne C Greene et al.
Biomaterials, 32(34), 8860-8869 (2011-09-03)
Chemical and topographical cues can be used to guide dissociated neurons into user-defined network geometries on artificial substrates, yet control of neuron polarity (differentiation into axons and dendrites) remains an elusive goal. We developed a dual guidance cue strategy for...
Natalie M Clark et al.
Chemical communications (Cambridge, England), (39)(39), 5835-5837 (2009-09-30)
'Conventional' (-)-sparteine adducts of lithium and sodium 1,1,1,3,3,3-hexamethyldisilazide (HMDS) were prepared and characterised, along with an unexpected and 'unconventional' hydroxyl-incorporated sodium sodiate, [(-)-sparteine x Na(mu-HMDS)Na x (-)-sparteine](+)[Na(4)(mu-HMDS)(4)(OH)](-)--the complex anion of which is the first inverse crown ether anion.
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