372439

Sigma-Aldrich

Perfluoro(methyldecalin), mixture of isomers

technical grade, 80%

Synonym(s):
Heptadecafluorodecahydro(trifluoromethyl)naphthalene
Empirical Formula (Hill Notation):
C11F20
CAS Number:
Molecular Weight:
512.09
PubChem Substance ID:
NACRES:
NA.22

grade

technical grade

Quality Level

assay

80%

refractive index

n20/D 1.317 (lit.)

bp

137-160 °C (lit.)

mp

−40 °C (lit.)

density

1.95 g/mL at 25 °C (lit.)

SMILES string

FC(F)(F)C1(F)C(F)(F)C(F)(F)C2(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C2(F)C1(F)F.FC(F)(F)C3(F)C(F)(F)C(F)(F)C(F)(F)C4(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C34F

InChI

1S/C11F20/c12-1-2(13,6(19,20)10(27,28)9(25,26)4(1,15)16)5(17,18)8(23,24)7(21,22)3(1,14)11(29,30)31

InChI key

LWRNQOBXRHWPGE-UHFFFAOYSA-N

Related Categories

General description

Perfluoro(methyldecalin) is a fluorinated solvent.

Application

Perfluoro(methyldecalin is suitable reagent used to investigate the reactions of iodide anions and anions derived from glow discharge ionization of perfluoro(methyldecalin) with positive ions derived from poly(ethylene glycol). It is suitable reagent used for the oxidation of alcohols with the ruthenium porphyrin at higher temperatures (140ºC) and elevated oxygen pressures (50psi). Perfluoro(methyldecalin (Perfluoro-1-Methyldecalin) may be used in the preparation of undecafluoro-6-trifluoromethyltetralin via defluorination.

Packaging

100 g in poly bottle

Other Notes

Contains perfluorodecalin

storage_class_code

10 - Combustible liquids

WGK Germany

WGK 3

Flash Point(F)

235.0 °F - closed cup

Flash Point(C)

112.80 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US),Eyeshields,Gloves

Certificate of Analysis

Certificate of Origin

Perfluoro-1-methyldecalin as a potential oxygen carrier with fluid scleral lenses.
M F Refojo et al.
Current eye research, 4(6), 732-733 (1985-06-01)
Michinao Hashimoto et al.
Small (Weinheim an der Bergstrasse, Germany), 3(10), 1792-1802 (2007-09-25)
A method is described for the formation of stable, composite aqueous emulsions of 1) combinations of distinct families of bubbles of nitrogen, 2) combinations of distinct families of droplets of an organic fluid (either perfluoro(methyl)decalin or hexadecane), and 3) combinations...
M K Bakulin et al.
Mikrobiologiia, 75(3), 371-376 (2006-07-29)
The isolates of pseudomonads (56) and of Plesiomonas shigelloides (7) exhibiting ice-forming activity were isolated from plant leaves and rhizosphere. The theoretical possibility of the application of perfluorocarbons (PFC) with a gas-transporting function (perfluorodecalin, carbogal, and perfluoromethyldecalin) for the cultivation...
Vasily N Korotchenko et al.
Organic & biomolecular chemistry, 6(11), 1961-1965 (2008-05-16)
Carbonylruthenium tetrakis(pentafluorophenyl)porphyrin Ru(TPFPP)(CO) was utilized for the aerobic oxidation of alcohols. The in situ activation of the catalyst with mCPBA provided a species capable of catalyzing the oxidation of alcohols with molecular oxygen. The choice of solvent and additive was...
Reactions of poly (ethylene glycol) cations with iodide and perfluorocarbon anions.
Stephenson Jr JM and McLuckey SA.
Journal of the American Society For Mass Spectrometry, 9(9), 957-965 (1998)

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service