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372870

Iron(II) chloride

98%, powder

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greener alternative

Greener Alternative

Synonym(s):

Ferrous chloride, Iron dichloride

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Size/SKUAvailabilityPrice
25 g

Available to ship TODAYfromMILWAUKEE

$113.00
250 g

Available to ship TODAYfromMILWAUKEE

$895.00
$760.75

About This Item

Linear Formula:
FeCl2
CAS Number:
Molecular Weight:
126.75
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12161600
EC Number:
231-843-4
MDL number:

$113.00

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Product Name

Iron(II) chloride, 98%

Quality Segment

assay

98%

form

powder

reaction suitability

core: iron, reagent type: catalyst
reaction type: Atom Transfer Radical Polymerization (ATRP)

greener alternative product characteristics

Catalysis
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

mp

677 °C (lit.)

density

3.16 g/mL at 25 °C (lit.)

greener alternative category

SMILES string

Cl[Fe]Cl

InChI

1S/2ClH.Fe/h2*1H;/q;;+2/p-2

InChI key

NMCUIPGRVMDVDB-UHFFFAOYSA-L

General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Green Chemistry. The iron catalysts are known to be inexpensive and environmentally benign. Click here for more information.

Application

Iron(II) chloride can be used to catalyze:
  • The preparation of Grignard compounds, such as 1-naphthylmagnesium chloride.
  • The selective oxidation of 2,4,6-trimethylphenol (2,4,6-TMP) to 3,5-dimethyl-4-hydroxybenzaldehyde (DMHB) in the presence of acetoxime.
  • Raney-type catalysts modified with FeCl2 show enhanced selective hydrogenation of an α,β-unsaturated aldehyde to an unsaturated alcohol.


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This Item
429368450936450944
description

98%

description

AnhydroBeads, −10 mesh, 99.998% trace metals basis

description

AnhydroBeads, −10 mesh, 99.99% trace metals basis

description

AnhydroBeads, −10 mesh, 99.9% trace metals basis

reaction suitability

reagent type: catalyst
reaction type: Atom Transfer Radical Polymerization (ATRP), core: iron

reaction suitability

core: iron

reaction suitability

core: iron

reaction suitability

core: iron, reagent type: catalyst

assay

98%

assay

99.998% trace metals basis

assay

99.99% trace metals basis

assay

99.9% trace metals basis

form

powder

form

beads

form

-

form

-

Quality Level

100

Quality Level

100

Quality Level

100

Quality Level

100

density

3.16 g/mL at 25 °C (lit.)

density

3.16 g/mL at 25 °C (lit.)

density

3.16 g/mL at 25 °C (lit.)

density

3.16 g/mL at 25 °C (lit.)

mp

677 °C (lit.)

mp

677 °C (lit.)

mp

677 °C (lit.)

mp

677 °C (lit.)


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pictograms

CorrosionExclamation mark

signalword

Danger

hcodes

Hazard Classifications

Acute Tox. 4 Oral - Eye Dam. 1

Storage Class

8B - Non-combustible corrosive hazardous materials

wgk

WGK 1

flash_point_f

does not flash

flash_point_c

does not flash

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges



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Certificates of Analysis (COA)

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Questions

1–4 of 4 Questions  
  1. Is this reagent anhydrous?

    1 answer
    1. This Iron(II) chloride product is not anhydrous. Please see the links below to review anhydrous Iron(II) chloride product options:
      https://www.sigmaaldrich.com/product/aldrich/450936
      https://www.sigmaaldrich.com/product/aldrich/450944
      https://www.sigmaaldrich.com/product/aldrich/429368

      Helpful?

  2. What color is it?

    1 answer
    1. The color of this Iron(II) chloride may range from beige to tan. The exact color is lot-specific nd reported in the Certificate of Analysis. Please see the link below to review a sample or lot specific Certificate:
      https://www.sigmaaldrich.com/product/aldrich/372870#product-documentation

      Helpful?

  3. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

      Helpful?

  4. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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