Nikolay V Orlov et al.
The Journal of organic chemistry, 79(24), 12111-12121 (2014-10-08)
A unique Ni-catalyzed transformation is reported for the one-pot highly selective synthesis of previously unknown monoseleno-substituted 1,3-dienes starting from easily available terminal alkynes and benzeneselenol. The combination of a readily available catalyst precursor, Ni(acac)2, and an appropriately tuned phosphine ligand...
Justin P Johnpeter et al.
Inorganic chemistry, 52(23), 13663-13673 (2013-11-20)
A series of cationic chalcogenolato-bridged diruthenium complexes [(η(6)-p-MeC6H4Pr(i))2Ru2(μ-EC6H5)3](+) (E = S, 1; E = Se, 2; E = Te, 3) has been obtained in ethanol from the reaction of (η(6)-p-MeC6H4Pr(i))2Ru2(μ-Cl)2Cl2 with benzenethiol, benzeneselenol, and sodium tellurophenolate, respectively. The thiolato and...
Brittany Trang et al.
Journal of the American Chemical Society, 140(42), 13892-13903 (2018-09-29)
Silver metal exposed to the atmosphere corrodes and becomes tarnished as a result of oxidation and precipitation of the metal as an insoluble salt. Tarnish has so poor a reputation that the word itself connotes corruption and disrespectability; however, tarnishing...
Diphenyl diselenide-promoted radical addition of benzeneselenol to acetylenes.
Ogawa A, et al.
Tetrahedron Letters, 33(10), 1329-1332 (1992)
David Crich et al.
Accounts of chemical research, 40(6), 453-463 (2007-05-11)
The discovery and development of the catalysis of stannane-mediated radical chain reactions by benzeneselenol, generated in situ by reduction of diphenyl diselenide with tributyltin hydride, are described. The catalytic sequence is discussed in terms of polarity reversal catalysis of radical...