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376612

Sigma-Aldrich

(1S)-10-Camphorsulfonamide

96%

Empirical Formula (Hill Notation):
C10H17NO3S
CAS Number:
Molecular Weight:
231.31
MDL number:
PubChem Substance ID:
NACRES:
NA.22

Quality Level

assay

96%

optical activity

[α]20/D +22°, c = 1 in methanol

mp

129-132 °C (lit.)

SMILES string

CC1(C)[C@@H]2CC[C@@]1(CS(N)(=O)=O)C(=O)C2

InChI

1S/C10H17NO3S/c1-9(2)7-3-4-10(9,8(12)5-7)6-15(11,13)14/h7H,3-6H2,1-2H3,(H2,11,13,14)/t7-,10-/m1/s1

InChI key

SBLUNABTQYDFJM-GMSGAONNSA-N

Related Categories

Application

(1S)-10-Camphorsulfonamide can be used:
  • As a template in molecule imprinted polymer (MIP) silica-based open tubular columns.
  • To prepare pyrrolidine–camphor based organocatalysts, applicable in Michael reaction of aldehydes with nitroalkenes.
  • To prepare prolyl sulfonamide organocatalysts, which are employed in the asymmetric Aldol reaction.

Packaging

1 g in glass bottle

Other Notes

Sign of optical rotation varies with solvent

Storage Class Code

13 - Non Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Certificate of Analysis

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Certificate of Origin

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