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378712

Sigma-Aldrich

(1S)-(+)-Menthyl chloroformate

optical purity ee: 97% (GLC)

Empirical Formula (Hill Notation):
C11H19ClO2
CAS Number:
Molecular Weight:
218.72
Beilstein:
2414685
MDL number:
PubChem Substance ID:
NACRES:
NA.22

form

liquid

Quality Level

optical activity

[α]20/D +83°, c = 1 in chloroform

optical purity

ee: 97% (GLC)

refractive index

n20/D 1.458 (lit.)

bp

108-109 °C/11 mmHg (lit.)

density

1.031 g/mL at 25 °C (lit.)

storage temp.

2-8°C

SMILES string

CC(C)[C@H]1CC[C@H](C)C[C@@H]1OC(Cl)=O

InChI

1S/C11H19ClO2/c1-7(2)9-5-4-8(3)6-10(9)14-11(12)13/h7-10H,4-6H2,1-3H3/t8-,9+,10-/m0/s1

InChI key

KIUPCUCGVCGPPA-AEJSXWLSSA-N

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Related Categories

Application

Chiral auxiliary in the asymmetric synthesis of quaternary carbon centers.

Packaging

5, 25 mL in glass bottle

Pictograms

CorrosionSkull and crossbones

Signal Word

Danger

Hazard Statements

Hazard Classifications

Acute Tox. 3 Inhalation - Skin Corr. 1B

Storage Class Code

6.1A - Combustible, acute toxic Cat. 1 and 2 / very toxic hazardous materials

WGK

WGK 3

Flash Point(F)

158.0 °F - closed cup

Flash Point(C)

70 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificate of Analysis

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Certificate of Origin

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