379387

Sigma-Aldrich

Dithiooxamide

97%

Synonym(s):
Dithiooxalic diamide, Rubeanic acid
Linear Formula:
NH2CSCSNH2
CAS Number:
Molecular Weight:
120.20
Beilstein/REAXYS Number:
605577
EC Number:
MDL number:
PubChem Substance ID:
NACRES:
NA.22
Pricing and availability is not currently available.

Quality Level

assay

97%

mp

≥300 °C (lit.)

solubility

ethanol: soluble 40 mg/10 mL, clear, red

SMILES string

NC(=S)C(N)=S

InChI

1S/C2H4N2S2/c3-1(5)2(4)6/h(H2,3,5)(H2,4,6)

InChI key

OAEGRYMCJYIXQT-UHFFFAOYSA-N

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General description

Dithiooxamide is reported to form complexes with Ni(II).

Application

Dithiooxamide may be used in the following studies:
  • Synthesis of thiazolothiazole-linked porous organic polymers under solvothermal conditions.
  • As modifier to prepare the modified glassy carbon electrode, used to investigate the electrochemical properties of quercetin, an important flavonoid derivative.
  • Synthesis of new chelating resin of dithiooxamide (rubeanic acid)-formaldehyde (DTOF), used in separation and concentration of silver ions.
  • Synthesis of N,N′-disubstituted dithiooxamides.

Packaging

5, 25 g in glass bottle

Pictograms

Exclamation mark

Signal Word

Warning

Hazard Statements

Precautionary Statements

Personal Protective Equipment

dust mask type N95 (US),Eyeshields,Gloves

Hazard Codes

Xn

Risk Statement

22-36/37/38

Safety Statement

36/37

RIDADR

NONH for all modes of transport

WGK Germany

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Nickel (II) complexes with dithiooxamide, N, N'-di-methyl-and N, N'-di-hydroxyethyl-dithiooxamide.
Peyronel G, et al.
Inorgorganica Chimica Acta, 5, 627-633 (1971)
Xiang Zhu et al.
Chemical communications (Cambridge, England), 50(95), 15055-15058 (2014-10-21)
Thiazolothiazole-linked porous organic polymers have been synthesized from a facile catalyst-free condensation reaction between aldehydes and dithiooxamide under solvothermal conditions. The resultant porous frameworks exhibit a highly selective uptake of CO2 over N2 under ambient conditions.
Preparation of Dithiooxamide Derivatives.
Hurd RN, et al.
The Journal of Organic Chemistry, 26(10), 3980-3987 (1961)
Z H Chohan et al.
Journal of inorganic biochemistry, 46(1), 41-48 (1992-04-01)
A number of cobalt(II) and nickel(II) complexes with novel dithiooxamide ligands derived from precursors such as benzonitrile, benzosulfonamide, benzaldehyde, benzoic acid, and phenol have been synthesized and characterized on the basis of their elemental analysis molar conductance, magnetic moment, H...
Bart Spee et al.
Journal of veterinary internal medicine, 20(5), 1085-1092 (2006-10-27)
Inherited defects of copper metabolism resulting in hepatic copper accumulation and oxidative-stress might cause breed-associated forms of hepatitis. Biliary excretion is the major elimination route of copper, therefore increased hepatic copper concentrations could also be caused by cholestasis. The aim...

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