If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf
383767
Tri(2-furyl)phosphine
99%, solid
Synonym(s):
TFP, Tri-2-furanylphosphine, Tris(2-furanyl)phosphine, Tris(o-furyl)phosphine
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$93.80
$93.80
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Product Name
Tri(2-furyl)phosphine, 99%
assay
99%
form
solid
reaction suitability
reagent type: ligand
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reagent type: ligand
reaction type: Cycloisomerizations
reagent type: ligand
reaction type: Heck Reaction
reagent type: ligand
reaction type: Negishi Coupling
reagent type: ligand
reaction type: Oxidations
reagent type: ligand
reaction type: Sonogashira Coupling
reagent type: ligand
reaction type: Stille Coupling
reagent type: ligand
reaction type: Suzuki-Miyaura Coupling
bp
136 °C/4 mmHg (lit.)
mp
59-64 °C (lit.)
functional group
phosphine
SMILES string
c1coc(c1)P(c2ccco2)c3ccco3
InChI
1S/C12H9O3P/c1-4-10(13-7-1)16(11-5-2-8-14-11)12-6-3-9-15-12/h1-9H
InChI key
DLQYXUGCCKQSRJ-UHFFFAOYSA-N
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This Item | 290572 | 666629 | 287822 |
|---|---|---|---|
| assay 99% | assay 97% | assay 97% | assay 97% |
| reaction suitability reagent type: ligand | reaction suitability - | reaction suitability - | reaction suitability - |
| functional group phosphine | functional group phosphine | functional group phosphine | functional group phosphine |
| form solid | form solid | form solid | form - |
| Quality Level 100 | Quality Level 200 | Quality Level 100 | Quality Level 200 |
| bp 136 °C/4 mmHg (lit.) | bp - | bp - | bp - |
Storage Class
11 - Combustible Solids
wgk_germany
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
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Phosphine Ligand Application Guide
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How is shipping temperature determined? And how is it related to the product storage temperature?
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Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf
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