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385638

Sigma-Aldrich

Di-(2-picolyl)amine

97%

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Synonym(s):
Bis(2-pyridylmethyl)amine
Empirical Formula (Hill Notation):
C12H13N3
CAS Number:
Molecular Weight:
199.25
EC Number:
MDL number:
PubChem Substance ID:
NACRES:
NA.22

assay

97%

refractive index

n20/D 1.578 (lit.)

bp

139-141 °C/1 mmHg (lit.)

solubility

water: soluble (partially miscible)(lit.)

density

1.107 g/mL at 25 °C (lit.)

SMILES string

C(NCc1ccccn1)c2ccccn2

InChI

1S/C12H13N3/c1-3-7-14-11(5-1)9-13-10-12-6-2-4-8-15-12/h1-8,13H,9-10H2

InChI key

KXZQYLBVMZGIKC-UHFFFAOYSA-N

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This Item
398179220523765880
vibrant-m

385638

Di-(2-picolyl)amine

vibrant-m

398179

Diethanolamine

vibrant-m

220523

(2-Methylbutyl)amine

solubility

water: soluble (partially miscible)(lit.)

solubility

water: soluble 105 g/L at 20 °C

solubility

alcohols and water: soluble(lit.)

solubility

-

assay

97%

assay

≥98.5%

assay

≥97%

assay

97%

density

1.107 g/mL at 25 °C (lit.)

density

1.097 g/mL at 25 °C (lit.)

density

0.738 g/mL at 25 °C (lit.)

density

-

bp

139-141 °C/1 mmHg (lit.)

bp

217 °C/150 mmHg (lit.)

bp

94-97 °C (lit.)

bp

-

refractive index

n20/D 1.578 (lit.)

refractive index

n20/D 1.477 (lit.)

refractive index

n20/D 1.4116 (lit.)

refractive index

-

Application

Di-(2-picolyl)amine can be used as:
  • A reactant to synthesize di(2-pyridylmethylamino)alkanoic esters using ω-iodoaliphatic carboxylic esters in the presence of triethylamine.
  • A ligand to synthesize iron complexes of di-(2-picolyl)amine by treating with iron trichloride, which can be used to catalyze the direct hydroxylation of benzene to phenol.
  • A reagent for the protection of carboxylic acids as carboxamides of bispicolylamine.

pictograms

Exclamation mark

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

10 - Combustible liquids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type ABEK (EN14387) respirator filter


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