385638

Di-(2-picolyl)amine

97%

• Synonym(s): Bis(2-pyridylmethyl)amine
• Empirical Formula (Hill Notation): C₁₂H₁₃N₃
• CAS Number: 1539-42-0
• Molecular Weight: 199.25
• EC Number: 216-266-8
• MDL number: MFCD00129044
• PubChem Substance ID: 24864040
• NACRES: NA.22

Properties

• Quality Level: 100
• assay: 97%
• refractive index: n20/D 1.578 (lit.)
• bp: 139-141 °C/1 mmHg (lit.)
• solubility: water: soluble (partially miscible)(lit.)
• density: 1.107 g/mL at 25 °C (lit.)
• SMILES string: C(NCc1ccccn1)c2ccccn2
• InChI: 1S/C12H13N3/c1-3-7-14-11(5-1)9-13-10-12-6-2-4-8-15-12/h1-8,13H,9-10H2
• InChI key: KXZQYLBVMZGIKC-UHFFFAOYSA-N

Description

Application

Di-(2-picolyl)amine can be used as:

• A reactant to synthesize di(2-pyridylmethylamino)alkanoic esters using ω-iodoaliphatic carboxylic esters in the presence of triethylamine.
• A ligand to synthesize iron complexes of di-(2-picolyl)amine by treating with iron trichloride, which can be used to catalyze the direct hydroxylation of benzene to phenol.
• A reagent for the protection of carboxylic acids as carboxamides of bispicolylamine.

Packaging

1, 5 g in glass bottle

Safety Information

• Pictograms: GHS07
• Signal Word: Warning
• Hazard Statements: H315 - H319 - H335
• Precautionary Statements: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• Hazard Classifications: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• Target Organs: Respiratory system
• Storage Class Code: 10 - Combustible liquids
• WGK: WGK 3
• Flash Point(F): Not applicable
• Flash Point(C): Not applicable
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves