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391220

Sigma-Aldrich

2-Chloro-1,3,2-dioxaphospholane

97%

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Synonym(s):
Cyclic ethylene chlorophosphite, Cyclic ethylene phosphorochloridite, Ethylene chlorophosphite, Ethylene glycol chlorophosphite
Empirical Formula (Hill Notation):
C2H4ClO2P
CAS Number:
Molecular Weight:
126.48
Beilstein/REAXYS Number:
506179
EC Number:
MDL number:
PubChem Substance ID:
NACRES:
NA.22

Quality Level

assay

97%

form

liquid

reaction suitability

reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand

refractive index

n20/D 1.489 (lit.)

bp

62 °C/20 mmHg (lit.)

density

1.422 g/mL at 25 °C (lit.)

storage temp.

2-8°C

SMILES string

ClP1OCCO1

InChI

1S/C2H4ClO2P/c3-6-4-1-2-5-6/h1-2H2

InChI key

OLSFRDLMFAOSIA-UHFFFAOYSA-N

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324124447536377953
2-Chloro-1,3,2-dioxaphospholane 97%

391220

2-Chloro-1,3,2-dioxaphospholane

reaction suitability

reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Hiyama Coupling, reaction type: Sonogashira Coupling, reaction type: Suzuki-Miyaura Coupling, reaction type: Negishi Coupling, reagent type: ligand, reaction type: Heck Reaction, reaction type: Stille Coupling

reaction suitability

reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: ligand

reaction suitability

reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: ligand

reaction suitability

-

form

liquid

form

solid

form

-

form

liquid

Quality Level

200

Quality Level

200

Quality Level

-

Quality Level

200

storage temp.

2-8°C

storage temp.

2-8°C

storage temp.

-

storage temp.

−20°C

density

1.422 g/mL at 25 °C (lit.)

density

-

density

1.149 g/mL at 25 °C (lit.)

density

1.55 g/mL at 25 °C (lit.)

Application

Phosphitylating agent used in the synthesis of phosphocholines and spirophosphoranes.

pictograms

CorrosionExclamation mark

signalword

Danger

Hazard Classifications

Skin Corr. 1B - STOT SE 3

target_organs

Respiratory system

supp_hazards

Storage Class

8A - Combustible, corrosive hazardous materials

wgk_germany

WGK 3

flash_point_f

186.8 °F - closed cup

flash_point_c

86 °C - closed cup

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter


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