395005

Supelco

N,N-Dimethylformamide di-tert-butyl acetal

for GC derivatization, LiChropur

Synonym(s):
1,1-Di-tert-butoxy-N,N-dimethylmethylamine, 1,1-Di-tert-butoxytrimethylamine
Linear Formula:
(CH3)2NCH[OC(CH3)3]2
CAS Number:
Molecular Weight:
203.32
Beilstein/REAXYS Number:
969629
EC Number:
MDL number:
PubChem Substance ID:
NACRES:
NA.22
Pricing and availability is not currently available.

Quality Level

grade

for GC derivatization

assay

≥90.0%

quality

LiChropur

reaction suitability

reagent type: derivatization reagent
reaction type: Acylations

application(s)

gas chromatography (GC): suitable

refractive index

n20/D 1.413 (lit.)

bp

56-57 °C/8 mmHg (lit.)

density

0.848 g/mL at 25 °C (lit.)

SMILES string

CN(C)C(OC(C)(C)C)OC(C)(C)C

InChI

1S/C11H25NO2/c1-10(2,3)13-9(12(7)8)14-11(4,5)6/h9H,1-8H3

InChI key

DBNQIOANXZVWIP-UHFFFAOYSA-N

Looking for similar products? Visit Product Comparison Guide

General description

N,N-Dimethylformamide di-tert-butyl acetal is an derivatizing reagent.

Packaging

10×1, 5, 25 mL in ampule
Clear borosilicate glass, high hydrolytic resistance (Type I)

Application

Reagent used for the preparation of indolizines via intermolecular cyclization of picolinium salts.
It was used as derivatizing agent in a study to determine cocaine and benzoyl ecgonine in urine using GC with on-column alkylation.

Legal Information

LiChropur is a trademark of Merck KGaA, Darmstadt, Germany

Pictograms

FlameExclamation mark

Signal Word

Warning

Hazard Statements

Target Organs

Respiratory system

Personal Protective Equipment

dust mask type N95 (US),Eyeshields,Gloves

RIDADR

UN 1993C 3 / PGIII

WGK Germany

WGK 3

Flash Point(F)

95.0 °F - closed cup

Flash Point(C)

35 °C - closed cup

Tetrahedron Letters, 47, 8817-8817 (2006)
N C Jain et al.
Journal of forensic sciences, 22(1), 7-16 (1977-01-01)
A gas chromatographic procedure has been developed for the simultaneous determination of cocaine and benzoyl ecgonine in urine specimens. The two drugs are extracted by isopropanol/chloroform from urine samples saturated with a bisalt buffer. The organic extract is evaporated to...

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service

Social Media

LinkedIn icon
Twitter icon
Facebook Icon
Instagram Icon

MilliporeSigma

Research. Development. Production.

We are a leading supplier to the global Life Science industry with solutions and services for research, biotechnology development and production, and pharmaceutical drug therapy development and production.

© 2021 Merck KGaA, Darmstadt, Germany and/or its affiliates. All Rights Reserved.

Reproduction of any materials from the site is strictly forbidden without permission.