402753

(−)-β-Pinene

≥99%

• Synonym(s): (1S,5S)-2(10)-Pinene, (1S,5S)-6,6-Dimethyl-2-methylenebicyclo3.1.1heptane, (-)-beta-Pinene, (1S)-(−)-β-Pinene
• Empirical Formula (Hill Notation): C₁₀H₁₆
• CAS Number: 18172-67-3
• Molecular Weight: 136.23
• Beilstein/REAXYS Number: 2038282
• EC Number: 242-060-2
• MDL number: MFCD00001345
• eCl@ss: 39011007
• PubChem Substance ID: 24865115
• NACRES: NA.22

Properties

• Quality Level: 100
• vapor density: 4.7 (vs air)
• vapor pressure: ~2 mmHg ( 20 °C)
• assay: ≥99%
• optical activity: α25/D −22°, neat
• optical purity: ee: 97% (GLC)
• refractive index: n20/D 1.478 (lit.)
• bp: 165-167 °C (lit.)
• mp: −61 °C (lit.)
• density: 0.866 g/mL at 25 °C
• SMILES string: HC@12CCC(=C)C@(H)(C1)C2(C)C
• InChI: 1S/C10H16/c1-7-4-5-8-6-9(7)10(8,2)3/h8-9H,1,4-6H2,2-3H3/t8-,9-/m0/s1
• InChI key: WTARULDDTDQWMU-IUCAKERBSA-N

Description

Application

(-)-β-Pinene has been used as a standard for the analysis of terpenoid compounds in plant essential oils by GC analysis. It may be used as a building block to synthesize natural products such as grandisol, robustadial and (+)-nopinone. (-)-β-Pinene undergoes hydroformylation in the presence of platinum/tin catalysts to form trans-10-formylpinane.

Packaging

1, 10 g in glass bottle

Safety Information

• Pictograms: GHS02,GHS07,GHS08,GHS09
• Signal Word: Danger
• Hazard Statements: H226 - H304 - H315 - H317 - H400
• Precautionary Statements: P210 - P273 - P280 - P301 + P310 + P331 - P302 + P352
• Personal Protective Equipment: dust mask type N95 (US),Eyeshields,Gloves
• Hazard Codes: Xn,N
• Risk Statement: 10-20/21/22-36/37/38-43-51-65
• Safety Statement: 16-26-36/37-46-61-62
• RIDADR: UN 2319 3 / PGIII
• WGK Germany: WGK 3
• Flash Point(F): 102.2 °F
• Flash Point(C): 39 °C