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403237

Dichlorobis(tricyclohexylphosphine)palladium(II)

95%, solid

Synonym(s):

PdCl2[P(cy)3]2

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$144.50

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$618.75

$144.50

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About This Item

Linear Formula:
[(C6H11)3P]2PdCl2
CAS Number:
Molecular Weight:
738.18
MDL number:
UNSPSC Code:
12161600
PubChem Substance ID:
NACRES:
NA.22

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Product Name

Dichlorobis(tricyclohexylphosphine)palladium(II), 95%

Quality Level

assay

95%

form

solid

reaction suitability

core: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Cross Couplings
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst

mp

270 °C (dec.) (lit.)

SMILES string

Cl[Pd]Cl.C1CCC(CC1)P(C2CCCCC2)C3CCCCC3.C4CCC(CC4)P(C5CCCCC5)C6CCCCC6

InChI

1S/2C18H33P.2ClH.Pd/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;;/h2*16-18H,1-15H2;2*1H;/q;;;;+2/p-2

InChI key

VUYVXCJTTQJVKJ-UHFFFAOYSA-L

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This Item
768111453048768103
reaction suitability

core: palladium, reaction type: Cross Couplings, reaction type: Hiyama Coupling, reaction type: Sonogashira Coupling, reaction type: Suzuki-Miyaura Coupling, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Negishi Coupling, reagent type: catalyst, reaction type: Stille Coupling, reaction type: Heck Reaction

reaction suitability

core: palladium, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Cross Couplings, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst

reaction suitability

-

reaction suitability

core: palladium, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Cross Couplings, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst

assay

95%

assay

97%

assay

97%

assay

95%

form

solid

form

solid

form

solid

form

solid

Quality Level

100

Quality Level

100

Quality Level

200

Quality Level

100

mp

270 °C (dec.) (lit.)

mp

230-300 °C (decomposition)

mp

280 °C (dec.) (lit.)

mp

260-264 °C (decomposition)

General description

Dichlorobis(tricyclohexylphosphine)palladium(II) is widely employed as catalyst precursor in various carbon-carbon and carbon-heteroatom bond forming reactions.[1]

Application

Catalyst for C-C and C-N coupling reaction.

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)


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Dichlorobis (tricyclohexylphosphine) palladium.
Carpentier JF, et al.
e-EROS Encyclopedia of Reagents for Organic Synthesis. (2008)

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