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406619

Hexadecafluorodecanedioic acid

Synonym(s):

Hexadecafluorosebacic acid, Perfluorodecanedioic acid, Perfluorosebacic acid

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About This Item

Linear Formula:
HOOC(CF2)8COOH
CAS Number:
307-78-8
Molecular Weight:
490.09
Beilstein/REAXYS Number:
1898292
MDL number:
MFCD00042365
UNSPSC Code:
12352100
PubChem Substance ID:
24865391
NACRES:
NA.22

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Quality Level

100

mp

151-160 °C (lit.)

functional group

carboxylic acid
fluoro

SMILES string

OC(=O)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(O)=O

InChI

1S/C10H2F16O4/c11-3(12,1(27)28)5(15,16)7(19,20)9(23,24)10(25,26)8(21,22)6(17,18)4(13,14)2(29)30/h(H,27,28)(H,29,30)

InChI key

YPCSMEGZIYWAAZ-UHFFFAOYSA-N

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This Item
171468164976402915
Hexadecafluorodecanedioic acid

Sigma-Aldrich

406619

Hexadecafluorodecanedioic acid

Perfluorooctanoic acid 95%

Sigma-Aldrich

171468

Perfluorooctanoic acid

α-Hydroxyisobutyric acid 98%

Sigma-Aldrich

164976

α-Hydroxyisobutyric acid

Phthalic acid ACS reagent, ≥99.5%

Sigma-Aldrich

402915

Phthalic acid

Quality Level

100

Quality Level

100

Quality Level

100

Quality Level

200

mp

151-160 °C (lit.)

mp

55-56 °C (lit.)

mp

76-80 °C (lit.)

mp

210-211 °C (dec.) (lit.)

functional group

carboxylic acid

functional group

-

functional group

carboxylic acid, hydroxyl

functional group

carboxylic acid

General description

Hexadecafluorodecanedioic acid (Hexadecafluorosebacic acid) is a perfluoroalkanedicarboxylic acid, useful in the preparation of synthetic polymers. Negative surface-assisted laser desorption/ionization (SALDI) mass spectra of hexadecafluorosebacic acid has been reported.[1]

Application

Hexadecafluorodecanedioic acid (Perfluorosebacic acid) may be employed as dopant for the synthesis of three-dimensional boxlike microstructures assembled from 1D-nanofibers of polyaniline (PANI).[2] It may be used for the synthesis of polymeric complex {[Mn(O2C(CF2)8CO2)(phen)2]H2O}n.[3]
Reactant involved in:
  • Studies of hydrogen peroxide disproportionation kinetics of manganese phenanthroline perfluorosebacato polymeric complex
  • Synthesis of cobalt phenanthroline perfluorosebacic acid complex
  • Reactions with zinc salt and phenanthroline

pictograms

Health hazardExclamation mark
GHS08,GHS07

signalword

Danger

Hazard Classifications

Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Carc. 2 - Lact. - Repr. 1B - STOT RE 1

target_organs

Liver

Storage Class

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
MKCT0836
MKCQ7440
MKCM9361
MKCJ7797
MKCC0274

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Synthesis, crystal structure and catalytic activity for H 2 O 2 disproportionation of the manganese (II) coordination polymer {[Mn (O 2 C (CF 2) 8 CO 2)(phen) 2] H 2 O} n (phen= 1, 10-phenanthroline).
Kani I, et al.
Polyhedron, 27(4), 1238-1247 (2008)
Chemical Ionization of Perfluoroalkanedicarboxylic Acid Compounds through Reduction of Copper (II) Sulfide by Laser Irradiation in Surface-Assisted Laser Desorption/Ionization Mass Spectrometry.
KAGAWA S and YOSHIOKA T.
Journal of Mass Spectrometry : Jms, 57(2) (2009)
3D-boxlike polyaniline microstructures with super-hydrophobic and high-crystalline properties.
Zhu Y, et al.
Polymer, 49(16), 3419-3423 (2008)

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