407429

Sigma-Aldrich

Methyl 3-methoxypropionate

≥99%

Linear Formula:
CH3OCH2CH2COOCH3
CAS Number:
Molecular Weight:
118.13
Beilstein/REAXYS Number:
1744829
EC Number:
MDL number:
PubChem Substance ID:
NACRES:
NA.22
Pricing and availability is not currently available.

Quality Level

assay

≥99%

refractive index

n20/D 1.402 (lit.)

bp

142-143 °C (lit.)

density

1.009 g/mL at 25 °C (lit.)

SMILES string

COCCC(=O)OC

InChI

1S/C5H10O3/c1-7-4-3-5(6)8-2/h3-4H2,1-2H3

InChI key

BDJSOPWXYLFTNW-UHFFFAOYSA-N

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General description

Methyl 3-methoxypropionate is an ester.

Application

Methyl 3-methoxypropionate may be employed as acylation reagent for the lipase-catalyzed N-acylation of 1-phenylethanamine. It may be used in the synthesis of poly(2-hydroxylethyl 5-norbornene-2-carboxylate /t-butyl 5-norbornene-2-carboxylate /5-norbornene-2-carboxylic acid /maleic anhydride) resists. Lithographic performance of these resists was studied using ArF stepper.

Packaging

1 L in glass bottle
250 mL in glass bottle

Pictograms

FlameExclamation mark

Signal Word

Warning

Hazard Statements

Target Organs

Respiratory system

Personal Protective Equipment

dust mask type N95 (US),Eyeshields,Gloves

Hazard Codes

Xi

Risk Statement

10-36/37/38

Safety Statement

26-36

RIDADR

UN 3272 3 / PGIII

WGK Germany

WGK 3

Flash Point(F)

116.6 °F - closed cup

Flash Point(C)

47 °C - closed cup

A Novel Alicyclic Polymers for 193nm Single Layer Resist Materials
Jung J-C, et al.
J. Photopolym. Sci. Technol., 11(3), 481-488 (1998)
Maria Cammenberg et al.
Chembiochem : a European journal of chemical biology, 7(11), 1745-1749 (2006-09-23)
One of the commercial methods for preparing enantiopure amines is lipase-catalyzed kinetic resolution, although lipases catalyze aminolysis with only low activity. Interestingly, in 1997 Balkenhohl et al. used ethyl methoxyacetate instead of ethyl butyrate as an acylation reagent for the...

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